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@ARTICLE{Ecker:890409,
author = {Ecker, Sabrina and Dornseiffer, J. and Werner, Jonas and
Schlenz, H. and Sohn, Y. J. and Sauerwein, F. S. and
Baumann, S. and Bouwmeester, H. J. M. and Guillon, O. and
Weirich, T. E. and Meulenberg, W. A.},
title = {{N}ovel low-temperature lean {NO}x storage materials based
on {L}a0.5{S}r0.5{F}e1-x{M}x{O}3-δ/{A}l2{O}3 infiltration
composites ({M} = {T}i, {Z}r, {N}b)},
journal = {Applied catalysis / B},
volume = {286},
issn = {0926-3373},
address = {Amsterdam},
publisher = {Elsevier},
reportid = {FZJ-2021-00936},
pages = {119919 -},
year = {2021},
abstract = {Low-temperature NOx storage materials for lean NOx traps
based on nanocomposites containing perovskite-type oxides of
La0.5Sr0.5Fe1-xMxO3-δ (M = Ti, Nb or Zr; x = 0.25 or 0.5)
are prepared in a highly porous alumina with different
loadings of 15−25 wt. $\%.$ The resulting storage
materials are characterised by X-ray diffraction, BET and
transmission electron microscopy with coupled ASTAR system
for crystallite phase mapping. For all nanocomposites high
surface areas around 100 m²/g are found. With perovskite
loadings of 20 wt. $\%$ the platinised composites reveal NOx
storage capacities between 120–164 μmol/g below 300 °C
with a performance ranking of Zr > Ti > Nb. After
hydrothermal ageing at 750 °C only for the Nb and Zr
containing composites a decrease of the NSC up to 20 $\%$
can be observed. The NSC of the LSFT system can be improved
by decreasing the perovskite loading to 15 wt. $\%.$},
cin = {IEK-1 / IEK-6 / JARA-ENERGY},
ddc = {540},
cid = {I:(DE-Juel1)IEK-1-20101013 / I:(DE-Juel1)IEK-6-20101013 /
$I:(DE-82)080011_20140620$},
pnm = {123 - Chemische Energieträger (POF4-123)},
pid = {G:(DE-HGF)POF4-123},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000621626700007},
doi = {10.1016/j.apcatb.2021.119919},
url = {https://juser.fz-juelich.de/record/890409},
}