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| 001 | 890434 | ||
| 005 | 20240712084617.0 | ||
| 024 | 7 | _ | |a 10.1039/D0RA10445K |2 doi |
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| 100 | 1 | _ | |a Zsabka, Peter |0 P:(DE-Juel1)169297 |b 0 |
| 245 | _ | _ | |a Selective extraction of trivalent actinides using CyMe4BTPhen in the ionic liquid Aliquat-336 nitrate |
| 260 | _ | _ | |a London |c 2021 |b RSC Publishing |
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| 520 | _ | _ | |a The extraction of Am(iii), Cm(iii) and Eu(iii) by 2,9-bis(5,5,8,8-tetramethyl-5,6,7,8-tetrahydro-1,2,4-benzotriazin-3-yl)-1,10-phenanthroline (CyMe4BTPhen) from nitric acid solution was studied using the ionic liquid Aliquat-336 nitrate ([A336][NO3]) as diluent. Results show a high selectivity of the solvent for Am(iii) and Cm(iii) over Eu(iii), but rather slow extraction kinetics. The kinetics of CyMe4BTPhen were largely improved by the addition of 0.005 mol L−1 N,N,N′,N′-tetra-n-octyl-diglycolamide (TODGA) as a phase transfer reagent and by the use of 1-octanol as co-diluent. The addition of the phase transfer catalyst and co-diluent did not compromise the selectivity towards the actinide/lanthanide separation and thus this four-component system can be successfully applied to separate Am(iii) and Cm(iii) from the lanthanides. |
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| 700 | 1 | _ | |a Van Hecke, Karen |0 0000-0002-7100-192X |b 1 |
| 700 | 1 | _ | |a Adriaensen, Lesley |0 P:(DE-HGF)0 |b 2 |
| 700 | 1 | _ | |a Wilden, Andreas |0 P:(DE-Juel1)130438 |b 3 |
| 700 | 1 | _ | |a Modolo, Giuseppe |0 P:(DE-Juel1)130383 |b 4 |
| 700 | 1 | _ | |a Verwerft, Marc |0 0000-0002-2385-6093 |b 5 |
| 700 | 1 | _ | |a Binnemans, Koen |0 0000-0003-4768-3606 |b 6 |
| 700 | 1 | _ | |a Cardinaels, Thomas |0 0000-0002-2695-1002 |b 7 |e Corresponding author |
| 773 | _ | _ | |a 10.1039/D0RA10445K |g Vol. 11, no. 11, p. 6014 - 6021 |0 PERI:(DE-600)2623224-8 |n 11 |p 6014 - 6021 |t RSC Advances |v 11 |y 2021 |x 2046-2069 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/890434/files/d0ra10445k.pdf |y OpenAccess |
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