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@ARTICLE{Montero:890940,
author = {Montero, Ana and Guimarães, Filipe Souza Mendes and
Lounis, Samir},
title = {{M}ultiple magnetic states of {C}o{P}c molecule on a
two-dimensional layer of {N}b{S}e 2},
journal = {Journal of physics / Condensed matter},
volume = {33},
number = {20},
issn = {0953-8984},
address = {Bristol},
publisher = {IOP Publ.},
reportid = {FZJ-2021-01262},
pages = {205802},
year = {2021},
abstract = {Molecular spintronics hinges on the detailed understanding
of electronic and magnetic properties of molecules
interfaced with various materials. Here we demonstrate with
ab-initio simulations that the prototypical
Co-phthalocyanine (CoPc) molecule can surprisingly develop
multi-spin states once deposited on the two-dimensional
2H-NbSe2 layer. Conventional calculations based on density
functional theory (DFT) show the existence of low, regular
and high spin states, which reduce to regular and high spins
states once correlations are incorporated with a DFT+U
approach. Depending on U, the ground state is either the low
spin or high spin state with energy differences affected by
the molecular orientation on top of the substrate. Our
results are compared to recent scanning probe measurements
and motivate further theoretical and experimental studies on
the unveiled rich multi-magnetic behavior of CoPc molecule.},
cin = {IAS-1 / PGI-1 / JARA-FIT / JARA-HPC / JSC},
ddc = {530},
cid = {I:(DE-Juel1)IAS-1-20090406 / I:(DE-Juel1)PGI-1-20110106 /
$I:(DE-82)080009_20140620$ / $I:(DE-82)080012_20140620$ /
I:(DE-Juel1)JSC-20090406},
pnm = {5211 - Topological Matter (POF4-521) / 5112 - Cross-Domain
Algorithms, Tools, Methods Labs (ATMLs) and Research Groups
(POF4-511)},
pid = {G:(DE-HGF)POF4-5211 / G:(DE-HGF)POF4-5112},
typ = {PUB:(DE-HGF)16},
pubmed = {33704093},
UT = {WOS:000645013500001},
doi = {10.1088/1361-648X/abed64},
url = {https://juser.fz-juelich.de/record/890940},
}