%0 Journal Article
%A Mücke, Robert
%A Finsterbusch, Martin
%A Kaghazchi, Payam
%A Fattakhova-Rohlfing, Dina
%A Guillon, Olivier
%T Modelling electro-chemical induced stresses in all-solid-state batteries: Anisotropy effects in cathodes and cell design optimisation
%J Journal of power sources
%V 489
%@ 0378-7753
%C New York, NY [u.a.]
%I Elsevier
%M FZJ-2021-01328
%P 229430
%D 2021
%X All-solid-state lithium batteries offer promising advantages in energy density and safety compared to conven­tional lithium ion batteries. However, the majority of this type of batteries suffers from a low cycling stability, which might originate from mechanical fatigue caused by mechanical stresses and strains in the rigid structure. We introduce a general approach to model and analyse the stresses in rigid cathode/electrolyte electrodes on a cell level, which enables to develop optimised cell designs with an improved mechanical stability. We apply this approach on composite cathodes with a Li7La3Zr2O12 (LLZO) ceramic electrolyte and LiCoO2 (LCO) active ma­terial. Using the 3D microstructure of a real cathode, the stresses inside a free-standing electrode and model cells with a thin and a thick LLZO separator are calculated for the charging cycle considering isotropic and anisotropic material properties of LCO as well as non-textured and textured crystallographic alignment. Compared to randomly oriented crystals, the textured crystallographic alignment of LCO grains, introduced by the manufacturing process, has a significant effect and yields considerably better stress distributions in all cell configurations investigated. The design of optimised all-solid-state cells with reduced separator thickness leads to a significantly more favourable stress state than a typical lab scale separator-supported cell.
%F PUB:(DE-HGF)16
%9 Journal Article
%U <Go to ISI:>//WOS:000619129700006
%R 10.1016/j.jpowsour.2020.229430
%U https://juser.fz-juelich.de/record/891042