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@ARTICLE{Huang:891077,
      author       = {Huang, Jun and Li, Chenkun},
      title        = {{I}mpedance {R}esponse of {E}lectrochemical {I}nterfaces:
                      {P}art {II} – {C}hemisorption},
      journal      = {Journal of physics / Condensed matter},
      volume       = {33},
      issn         = {0953-8984},
      address      = {Bristol},
      publisher    = {IOP Publ.},
      reportid     = {FZJ-2021-01348},
      pages        = {164003},
      year         = {2021},
      abstract     = {Physical modelling helps to acquire fundamental insights
                      from experimental data when electrochemical impedance
                      spectroscopy is employed for mechanistic understandings of
                      electrocatalytic reactions. Herein, we report an analytical
                      solution for chemisorption impedance from a consistent
                      treatment of ion transport in the solution and electron
                      transfer on the surface. Our formulation avoids both a
                      priori decoupling of double-layer charging and electron
                      transfer reaction, and a strict separation of double-layer
                      charging and ion transport. Ion transport in the entire
                      solution region is described by the Poisson-Nernst-Planck
                      theory and electron transfer kinetics on the electrode
                      surface by the Frumkin-Butler-Volmer theory. Surface dipoles
                      caused by partially charged chemisorbates are considered.
                      The classical Frumkin-Melik-Gaikazyan model for
                      chemisorption is retrieved as a limiting case. The obtained
                      formula is validated using experimental data of hydrogen
                      adsorption at Pt(111). Characteristic frequencies and
                      asymptotic behaviors of chemisorption impedance are
                      analyzed.},
      cin          = {IEK-13},
      ddc          = {530},
      cid          = {I:(DE-Juel1)IEK-13-20190226},
      pnm          = {122 - Elektrochemische Energiespeicherung (POF4-122)},
      pid          = {G:(DE-HGF)POF4-122},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {33730712},
      UT           = {WOS:000642192500001},
      doi          = {10.1088/1361-648X/abef9d},
      url          = {https://juser.fz-juelich.de/record/891077},
}