TY - JOUR
AU - Arbe, Arantxa
AU - Rubio, Jon
AU - Malo de Molina, Paula
AU - Maiz, Jon
AU - Pomposo, José A.
AU - Fouquet, Peter
AU - Prevost, Sylvain
AU - Juranyi, Fanni
AU - Khaneft, Marina
AU - Colmenero, Juan
TI - Melts of single-chain nanoparticles: A neutron scattering investigation
JO - Journal of applied physics
VL - 127
IS - 4
SN - 1089-7550
CY - Melville, NY
PB - American Inst. of Physics
M1 - FZJ-2021-01368
SP - 044305 -
PY - 2020
AB - The impact of purely intramolecular cross-linking on the properties of a polymer melt is studied by neutron diffraction and quasielastic incoherent and coherent neutron scattering on a system composed exclusively of single-chain nanoparticles. As a reference, a parallel study is presented on the melt of the linear precursor chains’ counterpart. Associated with structural heterogeneities provoked by the internal compartmentalization due to cross-links, a dramatic slowing down of the relaxation of density fluctuations is observed at intermediate length scales.
LB - PUB:(DE-HGF)16
UR - <Go to ISI:>//WOS:000515698500017
DO - DOI:10.1063/1.5140705
UR - https://juser.fz-juelich.de/record/891105
ER -