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@PHDTHESIS{Zeng:891152,
author = {Zeng, Fanlin},
title = {{M}echanical reliability and oxygen permeationof
{C}e0.8{G}d0.2{O}2-δ-{F}e{C}o2{O}4 dual phase membranes},
volume = {529},
school = {Univ. Twente},
type = {Dissertation},
address = {Jülich},
publisher = {Forschungszentrum Jülich GmbH Zentralbibliothek},
reportid = {FZJ-2021-01400},
isbn = {978-3-95806-527-7},
series = {Schriften des Forschungszentrums Jülich Reihe Energie $\&$
Umwelt / Energy $\&$ Environment},
pages = {IV, VI, 222},
year = {2021},
note = {Dissertation, Univ. Twente, 2021},
abstract = {Dual phase oxygen transport membranes, consisting of ionic
and electronicconducting phases, exhibit great potential in
high-purity oxygen generation due totheir high stability
under harsh application atmospheres. Oxygen-ion
conductivefluorite oxides (e.g. Ce0.8Gd0.2O2-δ) and
electron conductive spinel phases (e.g.FeCo2O4) are
promising material candidates for such a dual phase oxygen
transportmembrane. Mechanical properties (e.g. elastic
modulus, hardness, strength andsubcritical crack growth
behaviour) and oxygen permeation of the membrane
areimportant parameters regarding reliability for future
applications. These parametershave close relationships with
composition and microstructural characteristics, likegrain
size, phase distribution and defects (e.g. microcracks).
However, theserelationships are currently not fully
understood. Therefore, in this thesis, theinfluence of
composition, grain size and microstructural defects on
mechanicalproperties are investigated for
Ce0.8Gd0.2O2-δ-FeCo2O4 membranes. Millingprocedures during
powder fabrication and ceramic sintering profiles are
optimizedto overcome the formation of unfavorable
microstructural defects ...},
cin = {IEK-2},
cid = {I:(DE-Juel1)IEK-2-20101013},
pnm = {899 - ohne Topic (POF4-899)},
pid = {G:(DE-HGF)POF4-899},
typ = {PUB:(DE-HGF)3 / PUB:(DE-HGF)11},
url = {https://juser.fz-juelich.de/record/891152},
}