000891166 001__ 891166
000891166 005__ 20240712112816.0
000891166 0247_ $$2doi$$a10.1021/acsomega.1c00208
000891166 0247_ $$2Handle$$a2128/27969
000891166 0247_ $$2pmid$$a33869944
000891166 0247_ $$2WOS$$aWOS:000640649500033
000891166 037__ $$aFZJ-2021-01404
000891166 082__ $$a660
000891166 1001_ $$0P:(DE-Juel1)171551$$aHeuer, Sabrina A.$$b0
000891166 245__ $$aOxygen Nonstoichiometry and Valence State of Manganese in La 1– x Ca x MnO 3+δ
000891166 260__ $$aWashington, DC$$bACS Publications$$c2021
000891166 3367_ $$2DRIVER$$aarticle
000891166 3367_ $$2DataCite$$aOutput Types/Journal article
000891166 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1642773987_18986
000891166 3367_ $$2BibTeX$$aARTICLE
000891166 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000891166 3367_ $$00$$2EndNote$$aJournal Article
000891166 520__ $$aPerovskites of the ABO3 type, such as LaMnO3, can be used as air electrodes in solid oxide fuel cells and electrolyzers. Their properties can be tuned by A- and B-site substitutions. The influence of La substitution by Ca on the oxygen nonstoichiometry has been investigated frequently, but the results depend highly on the synthesis and atmospheric conditions. In this work, a series of La1–xCaxMnO3+δ (x = 0–0.5) was synthesized using conventional solid-state synthesis under an air atmosphere. The structures of the materials were studied in detail with powder X-ray diffraction. The initial oxygen nonstoichiometries were determined using thermogravimetric reduction. The samples were subsequently analyzed in terms of defect chemistry in dependence of temperature, atmosphere, and Ca content via thermogravimetric analysis. The changes in the manganese charge states were investigated by X-ray absorption near-edge spectroscopy experiments. The influence of intrinsic and extrinsic effects on the Mn-valence state of the differently Ca-substituted samples as calculated from thermogravimetric analysis and as determined directly from X-ray absorption near-edge spectroscopy is presented.
000891166 536__ $$0G:(DE-HGF)POF4-122$$a122 - Elektrochemische Energiespeicherung (POF4-122)$$cPOF4-122$$fPOF IV$$x0
000891166 536__ $$0G:(DE-HGF)POF4-1232$$a1232 - Power-based Fuels and Chemicals (POF4-123)$$cPOF4-123$$fPOF IV$$x1
000891166 588__ $$aDataset connected to CrossRef, Journals: juser.fz-juelich.de
000891166 7001_ $$0P:(DE-Juel1)161348$$aSchierholz, Roland$$b1$$eCorresponding author
000891166 7001_ $$0P:(DE-Juel1)144426$$aAlekseev, Evgeny$$b2
000891166 7001_ $$00000-0002-4677-850X$$aPeters, Lars$$b3
000891166 7001_ $$0P:(DE-Juel1)166093$$aMueller, David N.$$b4
000891166 7001_ $$0P:(DE-Juel1)165376$$aDuchoň, Tomáš$$b5
000891166 7001_ $$0P:(DE-Juel1)169490$$aVibhu, Vaibhav$$b6
000891166 7001_ $$0P:(DE-Juel1)161208$$aTempel, Hermann$$b7
000891166 7001_ $$0P:(DE-Juel1)129952$$ade Haart, L.G.J.$$b8$$ufzj
000891166 7001_ $$0P:(DE-Juel1)157700$$aKungl, Hans$$b9
000891166 7001_ $$0P:(DE-Juel1)156123$$aEichel, Rüdiger-A.$$b10
000891166 773__ $$0PERI:(DE-600)2861993-6$$a10.1021/acsomega.1c00208$$gVol. 6, no. 14, p. 9638 - 9652$$n14$$p9638 - 9652$$tACS omega$$v6$$x2470-1343$$y2021
000891166 8564_ $$uhttps://juser.fz-juelich.de/record/891166/files/Invoice_APC600200485.pdf
000891166 8564_ $$uhttps://juser.fz-juelich.de/record/891166/files/acsomega.1c00208.pdf$$yOpenAccess
000891166 8767_ $$8APC600200485$$92021-03-19$$d2021-03-23$$eAPC$$jZahlung erfolgt$$zUSD 1250,-, Belegnr. 1200165039 / 2021
000891166 909CO $$ooai:juser.fz-juelich.de:891166$$pdnbdelivery$$popenCost$$pVDB$$pdriver$$pOpenAPC$$popen_access$$popenaire
000891166 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)171551$$aForschungszentrum Jülich$$b0$$kFZJ
000891166 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)161348$$aForschungszentrum Jülich$$b1$$kFZJ
000891166 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)144426$$aForschungszentrum Jülich$$b2$$kFZJ
000891166 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)166093$$aForschungszentrum Jülich$$b4$$kFZJ
000891166 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)165376$$aForschungszentrum Jülich$$b5$$kFZJ
000891166 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)169490$$aForschungszentrum Jülich$$b6$$kFZJ
000891166 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)161208$$aForschungszentrum Jülich$$b7$$kFZJ
000891166 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)129952$$aForschungszentrum Jülich$$b8$$kFZJ
000891166 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)157700$$aForschungszentrum Jülich$$b9$$kFZJ
000891166 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)156123$$aForschungszentrum Jülich$$b10$$kFZJ
000891166 9101_ $$0I:(DE-588b)36225-6$$6P:(DE-Juel1)156123$$aRWTH Aachen$$b10$$kRWTH
000891166 9131_ $$0G:(DE-HGF)POF4-122$$1G:(DE-HGF)POF4-120$$2G:(DE-HGF)POF4-100$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$aDE-HGF$$bForschungsbereich Energie$$lMaterialien und Technologien für die Energiewende (MTET)$$vElektrochemische Energiespeicherung$$x0
000891166 9131_ $$0G:(DE-HGF)POF4-123$$1G:(DE-HGF)POF4-120$$2G:(DE-HGF)POF4-100$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF4-1232$$aDE-HGF$$bForschungsbereich Energie$$lMaterialien und Technologien für die Energiewende (MTET)$$vChemische Energieträger$$x1
000891166 9130_ $$0G:(DE-HGF)POF3-131$$1G:(DE-HGF)POF3-130$$2G:(DE-HGF)POF3-100$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$aDE-HGF$$bEnergie$$lSpeicher und vernetzte Infrastrukturen$$vElectrochemical Storage$$x0
000891166 9141_ $$y2021
000891166 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2021-01-29
000891166 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2021-01-29
000891166 915__ $$0LIC:(DE-HGF)CCBY4$$2HGFVOC$$aCreative Commons Attribution CC BY 4.0
000891166 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bACS OMEGA : 2019$$d2021-01-29
000891166 915__ $$0StatID:(DE-HGF)0501$$2StatID$$aDBCoverage$$bDOAJ Seal$$d2021-01-29
000891166 915__ $$0StatID:(DE-HGF)0500$$2StatID$$aDBCoverage$$bDOAJ$$d2021-01-29
000891166 915__ $$0StatID:(DE-HGF)0113$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2021-01-29
000891166 915__ $$0StatID:(DE-HGF)0700$$2StatID$$aFees$$d2021-01-29
000891166 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2021-01-29
000891166 915__ $$0StatID:(DE-HGF)9900$$2StatID$$aIF < 5$$d2021-01-29
000891166 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000891166 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bDOAJ : Blind peer review$$d2021-01-29
000891166 915__ $$0StatID:(DE-HGF)0561$$2StatID$$aArticle Processing Charges$$d2021-01-29
000891166 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2021-01-29
000891166 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2021-01-29
000891166 915__ $$0StatID:(DE-HGF)0320$$2StatID$$aDBCoverage$$bPubMed Central$$d2021-01-29
000891166 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2021-01-29
000891166 920__ $$lyes
000891166 9201_ $$0I:(DE-Juel1)IEK-9-20110218$$kIEK-9$$lGrundlagen der Elektrochemie$$x0
000891166 9201_ $$0I:(DE-Juel1)PGI-6-20110106$$kPGI-6$$lElektronische Eigenschaften$$x1
000891166 9801_ $$aAPC
000891166 9801_ $$aFullTexts
000891166 980__ $$ajournal
000891166 980__ $$aVDB
000891166 980__ $$aI:(DE-Juel1)IEK-9-20110218
000891166 980__ $$aI:(DE-Juel1)PGI-6-20110106
000891166 980__ $$aAPC
000891166 980__ $$aUNRESTRICTED
000891166 981__ $$aI:(DE-Juel1)IET-1-20110218