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@ARTICLE{Wang:891843,
      author       = {Wang, Haichao and Tang, Mingjin and Tan, Zhaofeng and Peng,
                      Chao and Keding, Lu},
      title        = {{A}tmospheric {C}hemistry of {N}itryl {C}hloride},
      journal      = {Huaxue-jinzhan},
      volume       = {32},
      number       = {10},
      issn         = {1005-281X},
      address      = {Beijing},
      reportid     = {FZJ-2021-01766},
      pages        = {1535-1546},
      year         = {2020},
      abstract     = {As an important reactive trace gases in the troposphere,
                      nitryl chloride (ClNO2) has significant impacts on
                      atmospheric oxidation capacity, the degradation of primary
                      pollutants and the formation of secondary pollutants, and
                      plays indispensable roles in global cycles of both nitrogen
                      and chlorine. In this paper, we introduce basic properties
                      of ClNO2 as well as its formation and removal mechanisms in
                      the troposphere, and describe in brief techniques currently
                      used in laboratory and field work to measure ClNO2. In
                      addition, we review spatial and temporal distributions of
                      tropospheric ClNO2 over the globe as reported in the last
                      10~20 years, discuss in a systematical manner chemical
                      mechanisms and environmental factors which determine its
                      heterogeneous formation in the atmosphere via critical
                      analysis of important results from laboratory studies and
                      field measurements, and summarize impacts of ClNO2 on
                      chlorine radicals, atmospheric oxidation capacity as well as
                      the formation of O3 and nitrate aerosol. We emphasize that
                      ClNO2 couples gas phase chemistry and heterogeneous
                      chemistry, and also couples nocturnal atmospheric chemistry
                      with daytime photochemistry, thus very likely playing an
                      important role in the formation of air pollution complex in
                      China. Important questions which remain to be answered to
                      better understand atmospheric chemistry of ClNO2 are
                      outlined at the end, and we also discuss in brief how these
                      questions can be addressed in future work.},
      cin          = {IEK-8},
      ddc          = {580},
      cid          = {I:(DE-Juel1)IEK-8-20101013},
      pnm          = {243 - Tropospheric trace substances and their
                      transformation processes (POF3-243)},
      pid          = {G:(DE-HGF)POF3-243},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000596561300008},
      doi          = {10.7536/PC200304},
      url          = {https://juser.fz-juelich.de/record/891843},
}