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@ARTICLE{Lewerenz:891992,
author = {Lewerenz, Meinert and Rahe, Christiane and Fuchs, Georg and
Endisch, Christian and Sauer, Dirk Uwe},
title = {{E}valuation of shallow cycling on two types of
uncompressed automotive
{L}i({N}i1/3{M}n1/3{C}o1/3){O}2-{G}raphite pouch cells},
journal = {Journal of energy storage},
volume = {30},
issn = {2352-152X},
address = {Amsterdam [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2021-01864},
pages = {101529 -},
year = {2020},
abstract = {For this contribution, two generations of uncompressed
pouch cells are investigated in cyclic aging tests. The
results are analyzed for the key influence factors by
opposing the results of both cell setup strategies with
results of compressed cells reported in literature. The
cells are evaluated with respect to pulse resistance, anode
overhang, dV/dQ-analysis, capacity difference analysis,
homogeneity of lithium distribution (HLD) and irreversible
capacity losses. It is shown, that uncompressed cells
reveal, in contrast to compressed cells, a higher HLD, which
is demonstrated in the missing dV/dQ flattening over aging.
The trends of peak heights in dV/dQ depend mainly on the
graphite voltage and expansion characteristics and are
therefore different for both cell generations due to
different degrees of utilization of the anode. The trends
are comparable to calendric aging test results. The
irreversible losses for uncompressed cycled cells increase
with cell potential while compressed cells show higher
losses to lower and higher SOCs caused by low HLD.
Therefore, uncompressed cells have a lower risk of
developing lithium plating for inhomogeneous distributed
active lithium during accelerated aging tests performing a
full charge. Comparing both cell generations, the lifetimes
show strong deviations and the largest impact is associated
with n/p ratio of the anode to the cathode.},
cin = {IEK-12},
ddc = {333.7},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000559030000004},
doi = {10.1016/j.est.2020.101529},
url = {https://juser.fz-juelich.de/record/891992},
}