% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Murmiliuk:892333,
      author       = {Murmiliuk, Anastasiia and Filippov, Sergey K. and Rud, Oleg
                      and Košovan, Peter and Tošner, Zdeněk and Radulescu,
                      Aurel and Skandalis, Athanasios and Pispas, Stergios and
                      Šlouf, Miroslav and Štěpánek, Miroslav},
      title        = {{R}eversible multilayered vesicle-like structures with
                      fluid hydrophobic and interpolyelectrolyte layers},
      journal      = {Journal of colloid and interface science},
      volume       = {599},
      issn         = {0021-9797},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2021-02004},
      pages        = {313 - 325},
      year         = {2021},
      abstract     = {Hydrophobic blocks of amphiphilic block copolymers often
                      form glassy micellar cores at room temperature with a rigid
                      structure that limits their applications as nanocapsules for
                      targeted delivery. Nevertheless, we prepared and analyzed
                      core/shell micelles with a soft core, formed by a
                      self-assembled block copolymer consisting of a hydrophobic
                      block and a polycation block, poly(lauryl
                      acrylate)-block-poly(trimethyl-aminoethyl acrylate)
                      (PLA-QPDMAEA), in aqueous solution. By light and small-angle
                      neutron scattering, by transmission electron microscopy and
                      by fluorescence spectroscopy, we showed that these
                      core/shell micelles are spherical and cylindrical with a
                      fluid-like PLA core and a positively charged outer shell and
                      that they can encapsulate and release hydrophobic solutes.
                      Moreover, after mixing these PLA-QPDMAEA core/shell micelles
                      with another diblock copolymer, consisting of a hydrophilic
                      block and a polyanion block, namely poly(ethylene
                      oxide)-block-poly(methacrylic acid) (PEO-PMAA), we observed
                      the formation of novel vesicle-like multicompartment
                      structures containing both soft hydrophobic and
                      interpolyelectrolyte (IPEC) layers. By combining small-angle
                      neutron scattering with self-consistent field modeling, we
                      confirmed the formation of these complex vesicle-like
                      structures with a swollen PEO core, an IPEC inner layer, a
                      PLA soft layer, an IPEC outer layer and a loose PEO corona.
                      Thus, these multicompartment micelles with fluid and IPEC
                      layers and a hydrophilic corona may be used as nanocapsules
                      with several tunable properties, including the ability to
                      control the thickness of each layer, the charge of the IPEC
                      layers and the stability of the micelles, to deliver both
                      hydrophobic and multivalent solutes.},
      cin          = {JCNS-FRM-II / MLZ / JCNS-4 / JCNS-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218 / I:(DE-588b)4597118-3 /
                      I:(DE-Juel1)JCNS-4-20201012 / I:(DE-Juel1)JCNS-1-20110106},
      pnm          = {6G4 - Jülich Centre for Neutron Research (JCNS) (FZJ)
                      (POF4-6G4) / 632 - Materials – Quantum, Complex and
                      Functional Materials (POF4-632)},
      pid          = {G:(DE-HGF)POF4-6G4 / G:(DE-HGF)POF4-632},
      experiment   = {EXP:(DE-MLZ)KWS2-20140101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {33957424},
      UT           = {WOS:000659386600005},
      doi          = {10.1016/j.jcis.2021.04.050},
      url          = {https://juser.fz-juelich.de/record/892333},
}