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@ARTICLE{Meister:892525,
author = {Meister, Paul and Küpers, Verena and Kolek, Martin and
Kasnatscheew, Johannes and Pohlmann, Sebastian and Winter,
Martin and Placke, Tobias},
title = {{E}nabling {M}g‐{B}ased {I}onic {L}iquid {E}lectrolytes
for {H}ybrid {D}ual‐{I}on {C}apacitors},
journal = {Batteries $\&$ supercaps},
volume = {4},
number = {3},
issn = {2566-6223},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2021-02133},
pages = {504 - 512},
year = {2021},
abstract = {We report on the reversible (de)intercalation of TFSI−
anions from a Mg‐based ionic liquid electrolyte, Mg(TFSI)2
in Pyr14TFSI, in graphite
urn:x-wiley:25666223:media:batt202000246:batt202000246-math-0001
activated carbon hybrid dual‐ion capacitor (DIC) cells.
The role of different pseudo reference electrodes (PREs)
including Ag‐wire and Li metal is discussed regarding the
comparability of different battery cells. We show that an
Ag‐wire PRE is not suitable for the designated purpose,
while the use of a Li metal PRE results in high
reproducibility. Mg‐based DIC cells are compared with
cells based on pure Pyr14TFSI and LiTFSI‐Pyr14TFSI
electrolytes, and with graphite
urn:x-wiley:25666223:media:batt202000246:batt202000246-math-0002
Li metal dual‐ion cells employing LiTFSI‐Pyr14TFSI. At
5.2 V vs. Li|Li+, Mg‐containing DIC cells reveal an
improved performance compared to Li‐based cells, i. e.,
higher capacity (87 vs. 85 mAh g−1) and higher
Coulombic efficiency (98 vs. $96 \%).$ These results may
pave the way to further studies and performance improvements
of Mg‐based batteries and to hybrid DIC chemistries with
other cations, especially multi‐valent ones.},
cin = {IEK-12},
ddc = {620},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {122 - Elektrochemische Energiespeicherung (POF4-122)},
pid = {G:(DE-HGF)POF4-122},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000597655900001},
doi = {10.1002/batt.202000246},
url = {https://juser.fz-juelich.de/record/892525},
}