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@ARTICLE{Yekta:892600,
author = {Yekta, Y. and Hadipour, H. and Sasioglu, Ersoy and
Friedrich, Christoph and Jafari, S. A. and Blügel, S. and
Mertig, I.},
title = {{S}trength of effective {C}oulomb interaction in
two-dimensional transition-metal halides {M} {X} 2 and {M}
{X} 3 ( {M} = {T}i , {V}, {C}r, {M}n, {F}e, {C}o, {N}i; {X}
= {C}l , {B}r, {I})},
journal = {Physical review materials},
volume = {5},
number = {3},
issn = {2475-9953},
address = {College Park, MD},
publisher = {APS},
reportid = {FZJ-2021-02190},
pages = {034001},
year = {2021},
abstract = {We calculate the strength of the effective on-site Coulomb
interaction (Hubbard U) in two-dimensional transition-metal
(TM) dihalides MX2 and trihalides MX3 (M=Ti, V, Cr, Mn, Fe,
Co, Ni; X=Cl, Br, I) from first principles using the
constrained random-phase approximation. The correlated
subspaces are formed from t2g or eg bands at the Fermi
energy. Elimination of the efficient screening taking place
in these narrow bands gives rise to sizable interaction
parameters U between the localized t2g (eg) electrons. Due
to this large Coulomb interaction, we find U/W>1 (with the
bandwidth W) in most TM halides, making them strongly
correlated materials. Among the metallic TM halides in the
paramagnetic state, the correlation strength U/W reaches a
maximum in NiX2 and CrX3 with values much larger than the
corresponding values in elementary TMs and other TM
compounds. Based on the Stoner model and the calculated U
and J values, we discuss the tendency of the electron spins
to order ferromagnetically.},
cin = {IAS-1 / PGI-1 / JARA-FIT / JARA-HPC},
ddc = {530},
cid = {I:(DE-Juel1)IAS-1-20090406 / I:(DE-Juel1)PGI-1-20110106 /
$I:(DE-82)080009_20140620$ / $I:(DE-82)080012_20140620$},
pnm = {521 - Quantum Materials (POF4-521)},
pid = {G:(DE-HGF)POF4-521},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000627661800001},
doi = {10.1103/PhysRevMaterials.5.034001},
url = {https://juser.fz-juelich.de/record/892600},
}