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000892610 1001_ $$0P:(DE-Juel1)187394$$aZhao, Yicheng$$b0$$eCorresponding author$$ufzj
000892610 245__ $$aDiscovery of temperature-induced stability reversal in perovskites using high-throughput robotic learning
000892610 260__ $$a[London]$$bNature Publishing Group UK$$c2021
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000892610 520__ $$aStability of perovskite-based photovoltaics remains a topic requiring further attention. Cation engineering influences perovskite stability, with the present-day understanding of the impact of cations based on accelerated ageing tests at higher-than-operating temperatures (e.g. 140°C). By coupling high-throughput experimentation with machine learning, we discover a weak correlation between high/low-temperature stability with a stability-reversal behavior. At high ageing temperatures, increasing organic cation (e.g. methylammonium) or decreasing inorganic cation (e.g. cesium) in multi-cation perovskites has detrimental impact on photo/thermal-stability; but below 100°C, the impact is reversed. The underlying mechanism is revealed by calculating the kinetic activation energy in perovskite decomposition. We further identify that incorporating at least 10 mol.% MA and up to 5 mol.% Cs/Rb to maximize the device stability at device-operating temperature (<100°C). We close by demonstrating the methylammonium-containing perovskite solar cells showing negligible efficiency loss compared to its initial efficiency after 1800 hours of working under illumination at 30°C.
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000892610 7001_ $$0P:(DE-HGF)0$$aZhang, Jiyun$$b1
000892610 7001_ $$0P:(DE-HGF)0$$aXu, Zhengwei$$b2
000892610 7001_ $$00000-0002-6179-1390$$aSun, Shijing$$b3
000892610 7001_ $$0P:(DE-Juel1)180636$$aLangner, Stefan$$b4
000892610 7001_ $$00000-0002-0748-0620$$aHartono, Noor Titan Putri$$b5
000892610 7001_ $$00000-0002-6974-410X$$aHeumueller, Thomas$$b6
000892610 7001_ $$00000-0002-1532-816X$$aHou, Yi$$b7
000892610 7001_ $$0P:(DE-HGF)0$$aElia, Jack$$b8
000892610 7001_ $$0P:(DE-Juel1)180778$$aLi, Ning$$b9
000892610 7001_ $$00000-0002-1138-3671$$aMatt, Gebhard J.$$b10
000892610 7001_ $$0P:(DE-Juel1)180633$$aDu, Xiaoyan$$b11
000892610 7001_ $$0P:(DE-HGF)0$$aMeng, Wei$$b12
000892610 7001_ $$0P:(DE-HGF)0$$aOsvet, Andres$$b13
000892610 7001_ $$0P:(DE-HGF)0$$aZhang, Kaicheng$$b14
000892610 7001_ $$0P:(DE-Juel1)176894$$aStubhan, Tobias$$b15
000892610 7001_ $$00000-0003-1302-7555$$aFeng, Yexin$$b16
000892610 7001_ $$0P:(DE-Juel1)177626$$aHauch, Jens$$b17
000892610 7001_ $$00000-0003-0396-6495$$aSargent, Edward H.$$b18
000892610 7001_ $$00000-0001-8345-4937$$aBuonassisi, Tonio$$b19
000892610 7001_ $$0P:(DE-Juel1)176427$$aBrabec, Christoph J.$$b20
000892610 773__ $$0PERI:(DE-600)2553671-0$$a10.1038/s41467-021-22472-x$$gVol. 12, no. 1, p. 2191$$n1$$p2191$$tNature Communications$$v12$$x2041-1723$$y2021
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