TY  - JOUR
AU  - Kulikovsky, Andrei
TI  - Impedance and Resistivity of Low–Pt Cathode in a PEM Fuel Cell
JO  - Journal of the Electrochemical Society
VL  - 168
IS  - 4
SN  - 1945-7111
CY  - Bristol
PB  - IOP Publishing
M1  - FZJ-2021-02302
SP  - 044512 -
PY  - 2021
AB  - Analysis of impedance model for the low–Pt cathode catalyst layer (CCL) in a PEM fuel cell is reported. The CCL is modeled as a cylindrical pore with the Nafion film separating the open pore volume from the Pt/C surface. In the limit of fast oxygen transport through the open pore, analytical expressions for the CCL impedance, Nafion film impedance and for the ohmic CCL resistivity Rccl (Ohm cm2) are derived. The characteristic frequency of film impedance is independent of film oxygen transport parameters and it is only 1.73 times less than the frequency of faradaic process in the CCL, which impedes separation of these processes by impedance spectroscopy. A fast version of algorithm for distrubution of relaxation times calculation is developed and used to illustrate the problem. Rccl exhibits rapid growth in the vicinity of limiting current density in the Nafion film, manifesting "overlinear" oxygen transport loss reported in experiments. For typical low–Pt cell parameters, this growth occurs at the cell current around 1 A cm−2. The model leads to a simple relation for the Nafion film transport resistivity ${{ \mathcal R }}_{N}$ (s cm−1); this relation is compared to semi–empirical and model relations available in literature.
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:000640599300001
DO  - DOI:10.1149/1945-7111/abf508
UR  - https://juser.fz-juelich.de/record/892744
ER  -