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100 1 _ |a Wang, Yuqi
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245 _ _ |a Symmetry mediated tunable molecular magnetism on a 2D material
260 _ _ |a London
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520 _ _ |a Symmetries in nanoscale structures can be decisive for their structural, electronic, and magnetic properties, particularly in systems with reduced dimensions. Here we show that the symmetries of a flat metal-organic molecule adsorbed on a transition metal dichalcogenide, a 2-dimensional layered material, have a dramatic effect on the total spin and the intramolecular spin-spin interactions. Using a scanning probe microscope, we find two different molecular spin states by modifying the symmetry of the molecules via the twist angle to the substrate. Additionally, we observe significant non-collinear Dzyaloshinskii–Moriya interaction between two electron spins on the molecule induced by the spin-orbit coupling of the van der Waals coupled layered material with broken inversion symmetry. Our work opens a path for modifying the spin by exploiting symmetries and for studying the nature of surface-induced non-collinear spin-spin interaction within a single molecule which might allow the realization of more complex topological spin structures.
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700 1 _ |a Arabi, Soroush
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700 1 _ |a Kern, Klaus
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700 1 _ |a Ternes, Markus
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773 _ _ |a 10.1038/s42005-021-00601-8
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