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@ARTICLE{Brownwood:892946,
      author       = {Brownwood, Bellamy and Turdziladze, Avtandil and Hohaus,
                      Thorsten and Wu, Rongrong and Mentel, Thomas F. and
                      Carlsson, Philip T. M. and Tsiligiannis, Epameinondas and
                      Hallquist, Mattias and Andres, Stefanie and Hantschke, Luisa
                      and Reimer, David and Rohrer, Franz and Tillmann, Ralf and
                      Winter, Benjamin and Liebmann, Jonathan and Brown, Steven S.
                      and Kiendler-Scharr, Astrid and Novelli, Anna and Fuchs,
                      Hendrik and Fry, Juliane},
      title        = {{G}as-{P}article {P}artitioning and {SOA} {Y}ields of
                      {O}rganonitrate {P}roducts from {NO} 3 -{I}nitiated
                      {O}xidation of {I}soprene under {V}aried {C}hemical
                      {R}egimes},
      journal      = {ACS earth and space chemistry},
      volume       = {5},
      number       = {4},
      issn         = {2472-3452},
      address      = {Washington, DC},
      publisher    = {ACS Publications},
      reportid     = {FZJ-2021-02445},
      pages        = {785 - 800},
      year         = {2021},
      abstract     = {Alkyl nitrate (AN) and secondary organic aerosol (SOA) from
                      the reaction of nitrate radicals (NO3) with isoprene were
                      observed in the Simulation of Atmospheric PHotochemistry In
                      a large Reaction (SAPHIR) chamber during the NO3Isop
                      campaign in August 2018. Based on 15 day-long experiments
                      under various reaction conditions, we conclude that the
                      reaction has a nominally unity molar AN yield (observed
                      range 90 ± $40\%)$ and an SOA mass yield of OA + organic
                      nitrate aerosol of $13–15\%$ (with ∼50 μg m–3
                      inorganic seed aerosol and 2–5 μg m–3 total organic
                      aerosol). Isoprene (5–25 ppb) and oxidant (typically
                      ∼100 ppb O3 and 5–25 ppb NO2) concentrations and aerosol
                      composition (inorganic and organic coating) were varied
                      while remaining close to ambient conditions, producing
                      similar AN and SOA yields under all regimes. We observe the
                      formation of dinitrates upon oxidation of the second double
                      bond only once the isoprene precursor is fully consumed. We
                      determine the bulk partitioning coefficient for ANs (Kp ∼
                      10–3 m3 μg–1), indicating an average volatility
                      corresponding to a C5 hydroxy hydroperoxy nitrate.},
      cin          = {IEK-8},
      ddc          = {550},
      cid          = {I:(DE-Juel1)IEK-8-20101013},
      pnm          = {211 - Die Atmosphäre im globalen Wandel (POF4-211)},
      pid          = {G:(DE-HGF)POF4-211},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {33889791},
      UT           = {WOS:000641221000004},
      doi          = {10.1021/acsearthspacechem.0c00311},
      url          = {https://juser.fz-juelich.de/record/892946},
}