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000893093 1001_ $$00000-0003-0909-2303$$aHamada, Takashi$$b0$$eCorresponding author
000893093 245__ $$aSynthesis and Characterization of 4‐Vinylimidazolium/Styrene‐Cografted Anion‐Conducting Electrolyte Membranes
000893093 260__ $$aWeinheim$$bWiley-VCH$$c2021
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000893093 520__ $$aThe β-hydrogen-free imidazole monomer, 2-methyl-N-methyl-4(5)-vinylimidazole (2M4VIm), is synthesized to prepare anion exchange membranes (AEMs). The radiation-induced graft polymerization of 2M4VIm and styrene is performed in poly(ethylene-co-tetrafluoroethylene), followed by N-alkylation and ion exchange reactions to prepare 4-vinylimidazolium-containing AEM (2M4VIm/St-AEM). AEMs that have a 6/4 2M4VIm/St molar ratio and 1.7 mmol g−1 ion exchange capacity (IEC) result in 75 mS cm−1 conductivity and 60% water uptake at room temperature in water, demonstrating enhanced values compared to previously reported 2-methyl-N-vinylimidazolium-containing AEMs (2MNVIm/St-AEM) that have a similar comonomer ratio and IEC. The small-angle neutron scattering measurements of dry and swollen 2M4VIm/St-AEM reveal hydrophilic/hydrophobic two-phase separation, as observed for 2MNVIm/St-AEM with a similar Im/St composition. 2M4VIm/St-AEMs exhibit higher alkaline stability in 1 m KOH at 80 °C at an early stage owing to the suppression of imidazolium β-elimination but lower long-term stability than that of 2MNVIm/St-AEM due to the ring-opening reaction of the imidazolium group due to its outward orientation from the graft main chain.
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000893093 65017 $$0V:(DE-MLZ)GC-1602-2016$$2V:(DE-HGF)$$aPolymers, Soft Nano Particles and  Proteins$$x0
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000893093 7001_ $$0P:(DE-HGF)0$$aYoshimura, Kimio$$b1
000893093 7001_ $$0P:(DE-HGF)0$$aTakeuchi, Kota$$b2
000893093 7001_ $$0P:(DE-HGF)0$$aWatanabe, Shun$$b3
000893093 7001_ $$00000-0001-5100-9230$$aZhao, Yue$$b4
000893093 7001_ $$0P:(DE-HGF)0$$aHiroki, Akihiro$$b5
000893093 7001_ $$0P:(DE-HGF)0$$aHagiwara, Tokio$$b6
000893093 7001_ $$0P:(DE-HGF)0$$aShishitani, Hideyuki$$b7
000893093 7001_ $$0P:(DE-HGF)0$$aYamaguchi, Susumu$$b8
000893093 7001_ $$0P:(DE-HGF)0$$aTanaka, Hirohisa$$b9
000893093 7001_ $$0P:(DE-Juel1)130905$$aRadulescu, Aurel$$b10
000893093 7001_ $$0P:(DE-HGF)0$$aOhwada, Kenji$$b11
000893093 7001_ $$0P:(DE-HGF)0$$aMaekawa, Yasunari$$b12$$eCorresponding author
000893093 773__ $$0PERI:(DE-600)1475026-0$$a10.1002/macp.202100028$$gp. 2100028 -$$n11$$p2100028$$tMacromolecular chemistry and physics$$v222$$x1521-3935$$y2021
000893093 8564_ $$uhttps://juser.fz-juelich.de/record/893093/files/Hamada%20et%20al_manuscript.pdf$$yPublished on 2021-06-01. Available in OpenAccess from 2022-06-01.
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