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100 1 _ |a Jaksch, Sebastian
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245 _ _ |a Influence of NaCl on the Structure and Dynamics of Phospholipid Layers
260 _ _ |a Lausanne
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520 _ _ |a We present a structural and dynamical analysis of the influence of NaCl on multilayer stacks of phospholipids on a solid surface. To this end, multilayer stacks of phospholipids (L-α-phosphatidylcholine, abbreviated as SoyPC) are investigated with neutron reflectometry, grazing-incidence small-angle neutron scattering (GISANS) and grazing-incidence neutron-spin echo spectroscopy (GINSES). We show both that the NaCl influence on the structure is predominantly on water-head group interface and also, that the change in dynamics is restricted to an associated change in the inter-plane viscosity. Using this knowledge, it is possible to model the dynamical behavior of a phospholipid membrane in response to a salt concentration of the solvent using only a single parameter, namely the in-plane viscosity. The excellent agreement with our previously published model also strongly supports the existence of a thermally excited surface mode in phospholipid membranes for close-to-physiological conditions.
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700 1 _ |a Frielinghaus, Henrich
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700 1 _ |a Koutsioubas, Alexandros
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700 1 _ |a Müller-Buschbaum, Peter
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773 _ _ |a 10.3389/fphy.2021.628219
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