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@ARTICLE{Zhao:893414,
      author       = {Zhao, Xin and Wu, Guixuan and Huang, Jin and Müller,
                      Michael},
      title        = {{I}nfluence of {H}2{O}/{HC}l/{H}2{S} containing gas
                      mixtures on condensation behavior of the trace metals lead
                      and cadmium under gasification-like conditions},
      journal      = {Fuel processing technology},
      volume       = {219},
      issn         = {0378-3820},
      address      = {New York, NY [u.a.]},
      publisher    = {Science Direct},
      reportid     = {FZJ-2021-02738},
      pages        = {106887 -},
      year         = {2021},
      abstract     = {In order to achieve an environmentally friendly treatment
                      of growing municipal solid waste, gasification technology as
                      a good candidate gains increasing attention and will play a
                      vital role in the processes of waste-to-energy. In this
                      study, the condensation behavior of trace metals Pb and Cd,
                      especially in HCl/H2S containing gas mixtures was
                      investigated under lab-scale gasification conditions. It was
                      found that PbO was a completely predominant condensation
                      species in atmospheres containing H2O or HCl while regarding
                      Cd condensation under identical conditions metallic Cd
                      prevails. It was also observed that the presence of 125 ppmv
                      HCl caused a significant shift of the condensation of PbO
                      from 790 to 670 °C. In the presence of H2S, the
                      condensation as sulfides, i.e. PbS and CdS occurred
                      overwhelmingly. A mechanism for the condensation of PbS was
                      proposed, with which an interesting phenomenon was
                      illuminated that the condensation of PbS moves to higher
                      temperatures as the H2S concentration increases from 125 to
                      250 ppmv, while it shifts towards lower temperatures with a
                      further concentration increase to 500 ppmv. In addition, the
                      difference in condensation mechanism for Cd and Pb was
                      compared and discussed.},
      cin          = {IEK-2},
      ddc          = {660},
      cid          = {I:(DE-Juel1)IEK-2-20101013},
      pnm          = {1221 - Fundamentals and Materials (POF4-122)},
      pid          = {G:(DE-HGF)POF4-1221},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000661887500003},
      doi          = {10.1016/j.fuproc.2021.106887},
      url          = {https://juser.fz-juelich.de/record/893414},
}