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@ARTICLE{Jantzen:893671,
      author       = {Jantzen, Tatjana and Yazhenskikh, Elena and Hack, Klaus and
                      Baben, Moritz to and Wu, Guixuan and Müller, Michael},
      title        = {{A}ddition of {V}2{O}5 and {V}2{O}3 to the
                      {C}a{O}–{F}e{O}–{F}e2{O}3–{M}g{O}–{S}i{O}2 database
                      for vanadium distribution and viscosity calculations},
      journal      = {Calphad},
      volume       = {74},
      issn         = {0364-5916},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier Science},
      reportid     = {FZJ-2021-02743},
      pages        = {102284 -},
      year         = {2021},
      abstract     = {Vanadium oxides were added to the existing GTOx database
                      because of its important role in the ferro-titanium
                      metallurgy as well as in petroleum coke gasification. The
                      CaO–FeO–Fe2O3–MgO–SiO2 system is a part of GTOx
                      database and is chosen because of the existence of
                      experimentally determined vanadium distributions between
                      vanadium ferroalloys and metallurgical slags. The
                      CaO–FeO–Fe2O3–MgO–SiO2–V2O3–V2O5 system
                      including all binary and ternary sub-systems was
                      thermodynamically assessed using all available experimental
                      data. Vanadium was introduced into the thermodynamic
                      description of solid solution phases such as MeO, Spinel,
                      Corundum and Ca2SiO4-α using available experimental
                      information. Particular attention was given to the phase
                      Spinel which forms the wide completely miscible solid
                      solution Fe3O4–FeV2O4–MgV2O4–MgFe2O4. The
                      thermodynamic description of the metallic vanadium
                      containing systems was taken from the SGTE alloy database.
                      With the knowledge about the complex behavior of vanadium in
                      slags as well as in liquid metal alloys it is possible to
                      calculate the vanadium distribution ratios (V)/[V] between
                      iron melts and slags in a wide range of temperatures and
                      compositions, corroborating the validity of the model under
                      reducing conditions. The additionally developed viscosity
                      model shows good agreement between the calculated and
                      experimental values in vanadium-containing slags.},
      cin          = {IEK-2},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-2-20101013},
      pnm          = {1221 - Fundamentals and Materials (POF4-122)},
      pid          = {G:(DE-HGF)POF4-1221},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000685205300004},
      doi          = {10.1016/j.calphad.2021.102284},
      url          = {https://juser.fz-juelich.de/record/893671},
}