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@ARTICLE{Liang:893907,
author = {Liang, Zhifu and Yang, Dawei and Tang, Pengyi and Zhang,
Chaoqi and Jacas Biendicho, Jordi and Zhang, Yi and Llorca,
Jordi and Wang, Xiang and Li, Junshan and Heggen, Marc and
David, Jeremy and Dunin-Borkowski, Rafal E. and Zhou,
Yingtang and Morante, Joan Ramon and Cabot, Andreu and
Arbiol, Jordi},
title = {{A}tomically dispersed {F}e in a {C} 2 {N} {B}ased
{C}atalyst as a {S}ulfur {H}ost for {E}fficient
{L}ithium–{S}ulfur {B}atteries},
journal = {Advanced energy materials},
volume = {11},
number = {5},
issn = {1614-6840},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2021-02919},
pages = {2003507 -},
year = {2021},
abstract = {Lithium–sulfur batteries (LSBs) are considered to be one
of the most promising next generation energy storage systems
due to their high energy density and low material cost.
However, there are still some challenges for the
commercialization of LSBs, such as the sluggish redox
reaction kinetics and the shuttle effect of lithium
polysulfides (LiPS). Here a 2D layered organic material,
C2N, loaded with atomically dispersed iron as an effective
sulfur host in LSBs is reported. X-ray absorption fine
spectroscopy and density functional theory calculations
prove the structure of the atomically dispersed Fe/C2N
catalyst. As a result, Fe/C2N-based cathodes demonstrate
significantly improved rate performance and long-term
cycling stability. Fe/C2N-based cathodes display initial
capacities up to 1540 mAh g−1 at 0.1 C and 678.7 mAh g−1
at 5 C, while retaining 496.5 mAh g−1 after 2600 cycles at
3 C with a decay rate as low as $0.013\%$ per cycle. Even at
a high sulfur loading of 3 mg cm−2, they deliver
remarkable specific capacity retention of 587 mAh g−1
after 500 cycles at 1 C. This work provides a rational
structural design strategy for the development of
high-performance cathodes based on atomically dispersed
catalysts for LSBs.},
cin = {ER-C-1},
ddc = {050},
cid = {I:(DE-Juel1)ER-C-1-20170209},
pnm = {5351 - Platform for Correlative, In Situ and Operando
Characterization (POF4-535) / ESTEEM3 - Enabling Science and
Technology through European Electron Microscopy (823717)},
pid = {G:(DE-HGF)POF4-5351 / G:(EU-Grant)823717},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000599600700001},
doi = {10.1002/aenm.202003507},
url = {https://juser.fz-juelich.de/record/893907},
}