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@ARTICLE{Nezhad:893909,
      author       = {Nezhad, Parastoo Delir Kheyrollahi and Bekheet, Maged F.
                      and Bonmassar, Nicolas and Schlicker, Lukas and Gili, Albert
                      and Kamutzki, Franz and Gurlo, Aleksander and Doran, Andrew
                      and Gao, Yuanxu and Heggen, Marc and Schwarz, Sabine and
                      Bernardi, Johannes and Niaei, Aligholi and Farzi, Ali and
                      Klötzer, Bernhard and Penner, Simon},
      title        = {{M}echanistic in situ insights into the formation,
                      structural and catalytic aspects of the {L}a2{N}i{O}4
                      intermediate phase in the dry reforming of methane over
                      {N}i-based perovskite catalysts},
      journal      = {Applied catalysis / A},
      volume       = {612},
      issn         = {0926-860X},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier Science},
      reportid     = {FZJ-2021-02921},
      pages        = {117984 -},
      year         = {2021},
      note         = {Bitte Post-print ergänzen},
      abstract     = {Parastoo Delir Kheyrollahi Nezhad; Maged Behkeet; Nicolas
                      Bonmassar; Lukas Schlicker; Albert Gili; Franz Kamutzki;
                      Andrew Doran; Yuanxu Gao; Marc Heggen; Sabine Schwarz;
                      Johannes Bernardi; Bernhard Klötzer; Aligholi Niaei; Ali
                      Farzi; and Simon Penner “Mechanistic In Situ Insights into
                      the Formation, Structural and Catalytic Aspects of the
                      La2NiO4 Intermediate Phase in the Dry Reforming of Methane
                      over Ni-based Perovskite Catalysts”, Applied Catalysis A,
                      Volume 612, (2021), 117984,
                      https://doi.org/10.1016/j.apcata.2020.117984Abstract:We
                      focus on the stability and bulk/surface structural
                      properties of the Ruddlesden-Popper phase La2NiO4 and their
                      consequences for dry reforming of methane (DRM) activity.
                      Fuelled by the appearance as a crucial intermediate during
                      in situ decomposition of highly DRM-active LaNiO3 perovskite
                      structures, we show that La2NiO4 can be equally in situ
                      decomposed into a Ni/La2O3 phase offering CO2 capture and
                      release necessary for DRM activity, albeit at much higher
                      temperatures compared to LaNiO3. Decomposition in hydrogen
                      also leads to an active Ni/La2O3 phase. In situ X-ray
                      diffraction during DRM operation reveals considerable coking
                      and encapsulation of exsolved Ni, yielding much smaller Ni
                      crystallites compared to on LaNiO3, where coking is
                      virtually absent. Generalizing the importance of
                      intermediate Ruddlesden-Popper phases, the in situ
                      decomposition of La-based perovskite structures yields
                      several obstacles due to the high stability of both the
                      parent perovskite and the Ruddlesden-Popper structures and
                      the occurrence of parasitic structures.},
      cin          = {ER-C-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)ER-C-1-20170209},
      pnm          = {5351 - Platform for Correlative, In Situ and Operando
                      Characterization (POF4-535)},
      pid          = {G:(DE-HGF)POF4-5351},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000672248500006},
      doi          = {10.1016/j.apcata.2020.117984},
      url          = {https://juser.fz-juelich.de/record/893909},
}