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000894082 1001_ $$0P:(DE-Juel1)169789$$aHussein, Mai$$b0$$eCorresponding author
000894082 245__ $$aActive participation of “inert” YSZ substrates on interface formation in Fe 3 O 4 /YSZ heterostructures
000894082 260__ $$aAmsterdam$$bElsevier$$c2021
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000894082 520__ $$aThe bulk and emerging interface properties of magnetite /YSZ(001) heterostructures grown by pulsed laser deposition are investigated. thin films (4–38 nm) grow epitaxially in (111) orientation and undergo a Verwey transition at max.  =  1170.6K. Surprisingly, the formation of interfacial Fe2O3 phase is observed albeit the quasi-inert properties of yttrium-stabilized zirconia (YSZ). Possible mechanisms include either (i) thermodynamically induced interfacial redox reaction at the YSZ substrate surfaces or (ii) oxygen diffusion from the outside atmosphere, as YSZ is a very good oxygen ion conductor. Hence, substrate-assisted oxygen supply may enable the control of emerging interface functionalities.
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000894082 7001_ $$0P:(DE-HGF)0$$aMueller, David N.$$b1
000894082 7001_ $$0P:(DE-Juel1)130854$$aMüller, Martina$$b2
000894082 773__ $$0PERI:(DE-600)2002520-8$$a10.1016/j.apsadv.2021.100132$$gVol. 6, p. 100132 -$$p100132 -$$tApplied surface science$$v6$$x0169-4332$$y2021
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