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@ARTICLE{Hussein:894082,
author = {Hussein, Mai and Mueller, David N. and Müller, Martina},
title = {{A}ctive participation of “inert” {YSZ} substrates on
interface formation in {F}e 3 {O} 4 /{YSZ} heterostructures},
journal = {Applied surface science},
volume = {6},
issn = {0169-4332},
address = {Amsterdam},
publisher = {Elsevier},
reportid = {FZJ-2021-03028},
pages = {100132 -},
year = {2021},
abstract = {The bulk and emerging interface properties of magnetite
/YSZ(001) heterostructures grown by pulsed laser deposition
are investigated. thin films (4–38 nm) grow epitaxially in
(111) orientation and undergo a Verwey transition at max. =
1170.6K. Surprisingly, the formation of interfacial Fe2O3
phase is observed albeit the quasi-inert properties of
yttrium-stabilized zirconia (YSZ). Possible mechanisms
include either (i) thermodynamically induced interfacial
redox reaction at the YSZ substrate surfaces or (ii) oxygen
diffusion from the outside atmosphere, as YSZ is a very good
oxygen ion conductor. Hence, substrate-assisted oxygen
supply may enable the control of emerging interface
functionalities.},
cin = {JCNS-2 / PGI-4 / JARA-FIT / PGI-6},
ddc = {660},
cid = {I:(DE-Juel1)JCNS-2-20110106 / I:(DE-Juel1)PGI-4-20110106 /
$I:(DE-82)080009_20140620$ / I:(DE-Juel1)PGI-6-20110106},
pnm = {632 - Materials – Quantum, Complex and Functional
Materials (POF4-632) / 6G4 - Jülich Centre for Neutron
Research (JCNS) (FZJ) (POF4-6G4)},
pid = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G4},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000739374600015},
doi = {10.1016/j.apsadv.2021.100132},
url = {https://juser.fz-juelich.de/record/894082},
}