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100 1 _ |a Hussein, Mai
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245 _ _ |a Active participation of “inert” YSZ substrates on interface formation in Fe 3 O 4 /YSZ heterostructures
260 _ _ |a Amsterdam
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520 _ _ |a The bulk and emerging interface properties of magnetite /YSZ(001) heterostructures grown by pulsed laser deposition are investigated. thin films (4–38 nm) grow epitaxially in (111) orientation and undergo a Verwey transition at max. = 1170.6K. Surprisingly, the formation of interfacial Fe2O3 phase is observed albeit the quasi-inert properties of yttrium-stabilized zirconia (YSZ). Possible mechanisms include either (i) thermodynamically induced interfacial redox reaction at the YSZ substrate surfaces or (ii) oxygen diffusion from the outside atmosphere, as YSZ is a very good oxygen ion conductor. Hence, substrate-assisted oxygen supply may enable the control of emerging interface functionalities.
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700 1 _ |a Mueller, David N.
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700 1 _ |a Müller, Martina
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773 _ _ |a 10.1016/j.apsadv.2021.100132
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