Hauptseite > Publikationsdatenbank > Evidence of anomalous conventional and spontaneous exchange bias, high coercivity in Fe doped NiCr2O4 spinel > print

001     894277
005     20220131120447.0
024 7 _ |a 10.1039/D0DT00124D
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024 7 _ |a 1470-479X
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024 7 _ |a 1477-9226
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024 7 _ |a 1477-9234
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024 7 _ |a 2050-5671
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024 7 _ |a 2128/28389
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037 _ _ |a FZJ-2021-03150
082 _ _ |a 540
100 1 _ |a Pandey, G. C.
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245 _ _ |a Evidence of anomalous conventional and spontaneous exchange bias, high coercivity in Fe doped NiCr2O4 spinel
260 _ _ |a London
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520 _ _ |a NiCr2−xFexO4 (x = 0 and 0.2) polycrystalline ceramics have been synthesized successfully through a simple co-precipitation technique to study the evolution of structural and magnetic properties by doping Fe. X-ray diffraction (XRD) reveals that the high-temperature cubic phase (space group Fd[3 with combining macron]m) observed at 320 K in bulk NiCr2O4 is stabilized at room temperature by decreasing the particle size to nanometer in x = 0 as well as after incorporating 20 at% Fe in the NiCr2O4 lattice. The cation distribution obtained from X-ray absorption fine structure (XAFS) analysis illustrates that while in x = 0, Ni2+ and Cr3+ ions occupy the tetrahedral (A) and octahedral (B) sites, respectively, x = 0.2, Fe3+ and Cr3+ ions occupy the A and B sites, respectively, and Ni2+ ions are distributed among the A and B sites. This transformation from the normal to mixed spinel structure strongly affects the magnetic properties. While the paramagnetic to long-range ferrimagnetic ordering temperature TC is enhanced from 71 to 192 K, significantly large coercive field (HC) of ∼29 kOe is observed for x = 0.2 as compared to the HC ∼13 kOe for x = 0. Moreover, unusually large conventional and spontaneous exchange bias fields of ∼26 and ∼2.6 kOe are observed for x = 0.2, which is absent for x = 0. The presence of anomalous exchange bias field is ascribed to the unidirectional exchange anisotropy between the two magnetic sublattices at A and B sites. The training effect of the exchange bias field is discussed using a phenomenological model, which considers the contribution from irreversible uncompensated spins that modify the exchange anisotropy at the interface between A and B magnetic sublattices. In addition, diffuse neutron scattering (DNS) with XYZ analysis is employed for both compositions to clearly illustrate the low-temperature peculiar magnetic phase transitions such as spin spiral transition, TS and spin lock-in transition, Tl. The DNS demonstrates that while Tl decreases from 10 K to 7 K with the incorporation of Fe in the NiCr2O4 lattice, TS significantly increases from 28 K to 50 K.
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693 _ _ |a Forschungs-Neutronenquelle Heinz Maier-Leibnitz
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700 1 _ |a Nemkovskiy, Kirill
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700 1 _ |a Su, Y.
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700 1 _ |a Rath, Chandana
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773 _ _ |a 10.1039/D0DT00124D
|g Vol. 49, no. 14, p. 4502 - 4517
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856 4 _ |u https://juser.fz-juelich.de/record/894277/files/d0dt00124d.pdf
856 4 _ |y Published on 2020-03-04. Available in OpenAccess from 2021-03-04.
|u https://juser.fz-juelich.de/record/894277/files/su_Dalton_2020_final_version.pdf
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