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@ARTICLE{Steffen:894586,
author = {Steffen, Alexandra and Glavic, Artur and Gutberlet, Thomas
and Ambaye, Haile and Schubert, Jürgen and Geprägs,
Stephan and Barthel, Juri and Mattauch, Stefan and Zander,
Willi and Kruth, Maximilian and Schöffmann, Patrick and
Pütter, Sabine and Brückel, Thomas},
title = {{U}nexpected precipitates in conjunction with
layer-by-layer growth in {M}n-enriched
{L}a2/3{S}r1/3{M}n{O}3 thin films},
journal = {Thin solid films},
volume = {735},
issn = {0040-6090},
address = {Amsterdam [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2021-03293},
pages = {138862 -},
year = {2021},
abstract = {In recent years, layer-by-layer heteroepitaxy has become a
versatile tool for depositing novel materials notaccessible
in bulk form. While it is possible to control the mono layer
sequence on an atomic scale with the helpof sophisticated
analysis techniques, not all important features of the thin
film growth are detectable. We reporton a detailed analysis
of layer-by-layer deposited Mn-enriched
La$_{2/3}$Sr$_{1/3}$MnO$_3$ thin films using various,
complementary experimental techniques. Our results show
that, contrary to the expectations from the growth
parameters and initial characterization, the films did not
grow as atomic planes but segregated into layers
ofLa$_{2/3}$Sr$_{1/3}$MnO$_{3}$ with additional embedded
precipitant crystals. We attribute this separation to a
Volmer-Weberisland-like growth of Mn$_3$O$_4$ crystals
within layers of La$_{2/3}$Sr$_{1/3}$MnO$_3$ due to
increased surface tension inhibiting La and Sr oxides from
sticking to nucleated Mn3O4 surfaces during the growth at
high temperatures.},
cin = {JCNS-4 / JCNS-2 / PGI-4 / JARA-FIT / JCNS-HBS / PGI-9 /
ER-C-2 / ER-C-1 / JCNS-FRM-II},
ddc = {660},
cid = {I:(DE-Juel1)JCNS-4-20201012 / I:(DE-Juel1)JCNS-2-20110106 /
I:(DE-Juel1)PGI-4-20110106 / $I:(DE-82)080009_20140620$ /
I:(DE-Juel1)JCNS-HBS-20180709 / I:(DE-Juel1)PGI-9-20110106 /
I:(DE-Juel1)ER-C-2-20170209 / I:(DE-Juel1)ER-C-1-20170209 /
I:(DE-Juel1)JCNS-FRM-II-20110218},
pnm = {632 - Materials – Quantum, Complex and Functional
Materials (POF4-632) / 6G4 - Jülich Centre for Neutron
Research (JCNS) (FZJ) (POF4-6G4)},
pid = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G4},
experiment = {EXP:(DE-MLZ)MBE-MLZ-20151210 / EXP:(DE-MLZ)MARIA-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000704918900006},
doi = {10.1016/j.tsf.2021.138862},
url = {https://juser.fz-juelich.de/record/894586},
}