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000008964 1001_ $$0P:(DE-Juel1)130718$$aHolderer, O.$$b0$$uFZJ
000008964 245__ $$aDynamical Properties of Decorated Lamellar Microemulsions in the Brush Regime
000008964 260__ $$aMünchen$$bOldenbourg$$c2010
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000008964 520__ $$aThe elastic constants of bicontinuous microemulsions, consisting of water, oil (decane) and a surfactant. can be modified by the addition of diblock-copolymers (boosting effect). A similar decoration of the surfactant membrane is possible in the lamellar phase. At high diblock copolymer densities, in the brush regime, a change in the dependence of the bending rigidity on the molecular size and concentration of the diblock copolymer is predicted theoretically. In particular a very strong dependence of the bending rigidity on the radius of gyration of the diblock copolymer (kappa proportional to R-5) is predicted. We have studied the structure and dynamics of lamellar microemulsions by small angle neutron scattering (SANS) and neutron spin echo spectroscopy (NSE) in the brush regime, with high diblock copolymer density. Decyl polyglycol ether (C10E4) has been used as surfactant, the amphiphilic diblock-copolymers were polyethylenepropylene/polyethyleneoxide (PEP5-PEO5). The influence of the diblock copolymer concentration when entering the brush regime on the bending rigidity K and the correlation length xi will be discussed.
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000008964 65320 $$2Author$$aLamellar Microemulsion
000008964 65320 $$2Author$$aBrush
000008964 65320 $$2Author$$aMushroom
000008964 65320 $$2Author$$aNeutron Scattering
000008964 65320 $$2Author$$aDynamics
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000008964 7001_ $$0P:(DE-Juel1)VDB4228$$aFrielinghaus, H.$$b1$$uFZJ
000008964 7001_ $$0P:(DE-HGF)0$$aByelov, D.$$b2
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000008964 8567_ $$uhttp://dx.doi.org/10.1524/zpch.2010.6102
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