TY - JOUR AU - Aguilera, Irene AU - Kim, Hyun-Jung AU - Friedrich, Christoph AU - Bihlmayer, Gustav AU - Blügel, Stefan TI - Z 2 topology of bismuth JO - Physical review materials VL - 5 IS - 9 SN - 2475-9953 CY - College Park, MD PB - APS M1 - FZJ-2021-03546 SP - L091201 PY - 2021 AB - While first-principles calculations with different levels of sophistication predict a topologically trivial Z2 state for bulk bismuth, some photoemission experiments show surface states consistent with the interpretation of bismuth being in a topologically nontrivial Z2 state. We resolve this contradiction between theory and experiment by showing, based on quasiparticle self-consistent GW calculations, that the experimental surface states interpreted as supporting a nontrivial phase are actually consistent with a trivial Z2 invariant. We identify this contradiction as the result of a crosstalk effect arising from the extreme penetration depth of the surface states into the bulk of Bi. A film of Bi can be considered bulklike only for thicknesses of about 1000 bilayers (≈400 nm) and more. LB - PUB:(DE-HGF)16 UR - <Go to ISI:>//WOS:000705548700005 DO - DOI:10.1103/PhysRevMaterials.5.L091201 UR - https://juser.fz-juelich.de/record/896713 ER -