% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Ye:897254,
      author       = {Ye, Ruijie and Ihrig, Martin and Imanishi, Nobuyuki and
                      Finsterbusch, Martin and Figgemeier, Egbert},
      title        = {{A} {R}eview on {L}i + /{H} + {E}xchange in {G}arnet
                      {S}olid {E}lectrolytes: {F}rom {I}nstability against
                      {H}umidity to {S}ustainable {P}rocessing in {W}ater},
      journal      = {ChemSusChem},
      volume       = {14},
      number       = {20},
      issn         = {1864-564X},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2021-03716},
      pages        = {4397-4407},
      year         = {2021},
      abstract     = {Garnet-based Li-ion conductors are one of the most
                      promising oxide-ceramic solid electrolytes for
                      next-generation Li batteries. However, they undergo a Li+/H+
                      exchange (LHX) reaction with most protic solvents used in
                      component manufacturing routes and even with moisture in
                      ambient air. These protonated garnets show a lower Li-ionic
                      conductivity, and even if only the surface is protonated,
                      this degraded layer hinders the Li-ion exchange with, for
                      example, a metallic Li anode. Furthermore, the resulting
                      unstable surface properties during the processing in air
                      lead to challenges with respect to reproducibility of the
                      final component performance, limiting their commercial
                      applicability. However, in recent years, the knowledge about
                      the underlying chemical mechanisms has led to the
                      development of mitigation strategies and enabled a push of
                      this promising material class towards sustainable and
                      scalable fabrication routes. This Minireview covers the
                      following four aspects, which are relevant for a
                      comprehensive understanding of these developments: (1)
                      reports of LHX phenomenon in garnets exposed to air and
                      solvents; (2) recent understandings of the fundamentals and
                      properties of LHX; (3) strategies to prevent LHX and to
                      recover garnets; and (4) sustainable application of LHX for
                      material processing and energy-related devices.},
      cin          = {IEK-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-1-20101013},
      pnm          = {1122 - Design, Operation and Digitalization of the Future
                      Energy Grids (POF4-112)},
      pid          = {G:(DE-HGF)POF4-1122},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:34264021},
      UT           = {WOS:000681376500001},
      doi          = {10.1002/cssc.202101178},
      url          = {https://juser.fz-juelich.de/record/897254},
}