Hauptseite > Publikationsdatenbank > Hydrophobic Effect on Alkaline Stability of Graft Chains in Ammonium‐type Anion Exchange Membranes Prepared by Radiation‐Induced Graft Polymerization > print

001     897357
005     20220222143556.0
024 7 _ |a 10.1002/slct.202102045
|2 doi
024 7 _ |a 2128/28722
|2 Handle
024 7 _ |a altmetric:113401328
|2 altmetric
024 7 _ |a WOS:000693218500049
|2 WOS
037 _ _ |a FZJ-2021-03745
082 _ _ |a 540
100 1 _ |a Hamada, Takashi
|0 P:(DE-HGF)0
|b 0
|e Corresponding author
245 _ _ |a Hydrophobic Effect on Alkaline Stability of Graft Chains in Ammonium‐type Anion Exchange Membranes Prepared by Radiation‐Induced Graft Polymerization
260 _ _ |a Weinheim
|c 2021
|b Wiley-VCH
336 7 _ |a article
|2 DRIVER
336 7 _ |a Output Types/Journal article
|2 DataCite
336 7 _ |a Journal Article
|b journal
|m journal
|0 PUB:(DE-HGF)16
|s 1645451162_27837
|2 PUB:(DE-HGF)
336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a Journal Article
|0 0
|2 EndNote
520 _ _ |a Vinylbenzyltrimethylammonium hydroxide (VBA) and styrene (St) cografted poly(ethylene-co-tetrafluoroethylene) anion exchange membranes (VBA/St-AEM) were prepared by the radiation-induced graft polymerization of chloromethylstyrene and St and sequential quaternization and anion exchange reactions. Increasing the St content in the grafts to 63 % resulted in a gradual 21 % and 34 % decrease in the conductivity and water uptake, respectively, compared to those in the VBA-homo-grafted AEM. AEMs with a higher St content (81 %) showed a 9 % and 18 % higher conductivity and water uptake, respectively. Small-angle neutron scattering showed that the sudden growth of “water puddles” consisting of water-rich nano-domains dispersed randomly in phase-separated hydrophilic ion channels enhanced the conductivity and water uptake. In the alkaline durability test of VBA/St-AEM in 1 M potassium hydroxide at 80 °C for 720 h, the loss of the conductivity was suppressed from 43 % to 8 %, when the St contents in the grafts were increased from 0 % to 63 %.
536 _ _ |a 6G4 - Jülich Centre for Neutron Research (JCNS) (FZJ) (POF4-6G4)
|0 G:(DE-HGF)POF4-6G4
|c POF4-6G4
|f POF IV
|x 0
536 _ _ |a 632 - Materials – Quantum, Complex and Functional Materials (POF4-632)
|0 G:(DE-HGF)POF4-632
|c POF4-632
|f POF IV
|x 1
588 _ _ |a Dataset connected to CrossRef, Journals: juser.fz-juelich.de
650 2 7 |a Soft Condensed Matter
|0 V:(DE-MLZ)SciArea-210
|2 V:(DE-HGF)
|x 0
650 2 7 |a Materials Science
|0 V:(DE-MLZ)SciArea-180
|2 V:(DE-HGF)
|x 1
650 1 7 |a Polymers, Soft Nano Particles and Proteins
|0 V:(DE-MLZ)GC-1602-2016
|2 V:(DE-HGF)
|x 0
693 _ _ |a Forschungs-Neutronenquelle Heinz Maier-Leibnitz
|e KWS-2: Small angle scattering diffractometer
|f NL3ao
|1 EXP:(DE-MLZ)FRMII-20140101
|0 EXP:(DE-MLZ)KWS2-20140101
|5 EXP:(DE-MLZ)KWS2-20140101
|6 EXP:(DE-MLZ)NL3ao-20140101
|x 0
700 1 _ |a Zhao, Yue
|0 P:(DE-HGF)0
|b 1
700 1 _ |a Yoshimura, Kimio
|0 P:(DE-HGF)0
|b 2
700 1 _ |a Radulescu, Aurel
|0 P:(DE-Juel1)130905
|b 3
700 1 _ |a Ohwada, Kenji
|0 P:(DE-HGF)0
|b 4
700 1 _ |a Maekawa, Yasunari
|0 P:(DE-HGF)0
|b 5
|e Corresponding author
773 _ _ |a 10.1002/slct.202102045
|g Vol. 6, no. 33, p. 8879 - 8888
|0 PERI:(DE-600)2844262-3
|n 33
|p 8879 - 8888
|t ChemistrySelect
|v 6
|y 2021
|x 2365-6549
856 4 _ |u https://juser.fz-juelich.de/record/897357/files/Hamada%20et%20al_final%20version.pdf
|y Published on 2021-09-06. Available in OpenAccess from 2022-09-06.
856 4 _ |u https://juser.fz-juelich.de/record/897357/files/slct.202102045.pdf
|y Restricted
909 C O |o oai:juser.fz-juelich.de:897357
|p openaire
|p open_access
|p driver
|p VDB:MLZ
|p VDB
|p dnbdelivery
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 3
|6 P:(DE-Juel1)130905
913 1 _ |a DE-HGF
|b Forschungsbereich Materie
|l Großgeräte: Materie
|1 G:(DE-HGF)POF4-6G0
|0 G:(DE-HGF)POF4-6G4
|3 G:(DE-HGF)POF4
|2 G:(DE-HGF)POF4-600
|4 G:(DE-HGF)POF
|v Jülich Centre for Neutron Research (JCNS) (FZJ)
|x 0
913 1 _ |a DE-HGF
|b Forschungsbereich Materie
|l From Matter to Materials and Life
|1 G:(DE-HGF)POF4-630
|0 G:(DE-HGF)POF4-632
|3 G:(DE-HGF)POF4
|2 G:(DE-HGF)POF4-600
|4 G:(DE-HGF)POF
|v Materials – Quantum, Complex and Functional Materials
|x 1
914 1 _ |y 2021
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0200
|2 StatID
|b SCOPUS
|d 2021-01-28
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0160
|2 StatID
|b Essential Science Indicators
|d 2021-01-28
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0600
|2 StatID
|b Ebsco Academic Search
|d 2021-01-28
915 _ _ |a Embargoed OpenAccess
|0 StatID:(DE-HGF)0530
|2 StatID
915 _ _ |a JCR
|0 StatID:(DE-HGF)0100
|2 StatID
|b CHEMISTRYSELECT : 2019
|d 2021-01-28
915 _ _ |a DEAL Wiley
|0 StatID:(DE-HGF)3001
|2 StatID
|d 2021-01-28
|w ger
915 _ _ |a WoS
|0 StatID:(DE-HGF)0113
|2 StatID
|b Science Citation Index Expanded
|d 2021-01-28
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0150
|2 StatID
|b Web of Science Core Collection
|d 2021-01-28
915 _ _ |a IF < 5
|0 StatID:(DE-HGF)9900
|2 StatID
|d 2021-01-28
915 _ _ |a Peer Review
|0 StatID:(DE-HGF)0030
|2 StatID
|b ASC
|d 2021-01-28
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)1150
|2 StatID
|b Current Contents - Physical, Chemical and Earth Sciences
|d 2021-01-28
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0300
|2 StatID
|b Medline
|d 2021-01-28
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0199
|2 StatID
|b Clarivate Analytics Master Journal List
|d 2021-01-28
920 _ _ |l yes
920 1 _ |0 I:(DE-Juel1)JCNS-FRM-II-20110218
|k JCNS-FRM-II
|l JCNS-FRM-II
|x 0
920 1 _ |0 I:(DE-588b)4597118-3
|k MLZ
|l Heinz Maier-Leibnitz Zentrum
|x 1
920 1 _ |0 I:(DE-Juel1)JCNS-4-20201012
|k JCNS-4
|l JCNS-4
|x 2
980 _ _ |a journal
980 _ _ |a VDB
980 _ _ |a I:(DE-Juel1)JCNS-FRM-II-20110218
980 _ _ |a I:(DE-588b)4597118-3
980 _ _ |a I:(DE-Juel1)JCNS-4-20201012
980 _ _ |a UNRESTRICTED
980 1 _ |a FullTexts

LibraryCollectionCLSMajorCLSMinorLanguageAuthor
Marc 21