000901993 001__ 901993
000901993 005__ 20211130111102.0
000901993 0247_ $$2doi$$a10.1021/acs.jpclett.1c02115
000901993 0247_ $$2Handle$$a2128/28840
000901993 0247_ $$2pmid$$a34647748
000901993 0247_ $$2WOS$$aWOS:000711025300029
000901993 037__ $$aFZJ-2021-03960
000901993 082__ $$a530
000901993 1001_ $$0P:(DE-HGF)0$$avan Spronsen, Matthijs A.$$b0$$eCorresponding author
000901993 245__ $$aInterface Sensitivity in Electron/Ion Yield X-ray Absorption Spectroscopy: The TiO2–H2O Interface
000901993 260__ $$aWashington, DC$$bACS$$c2021
000901993 3367_ $$2DRIVER$$aarticle
000901993 3367_ $$2DataCite$$aOutput Types/Journal article
000901993 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1635161040_32551
000901993 3367_ $$2BibTeX$$aARTICLE
000901993 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000901993 3367_ $$00$$2EndNote$$aJournal Article
000901993 520__ $$aTo understand corrosion, energy storage, (electro)catalysis, etc., obtaining chemical information on the solid–liquid interface is crucial but remains extremely challenging. Here, X-ray absorption spectroscopy (XAS) is used to study the solid–liquid interface between TiO2 and H2O. A thin film (6.7 nm) of TiO2 is deposited on an X-ray-transparent SiNx window, acting as the working electrode in a three-electrode flow cell. The spectra are collected based on the electron emission resulting from the decay of the X-ray-induced core-hole-excited atoms, which we show is sensitive to the solid–liquid interface within a few nm. The drain currents measured at the working and counter electrodes are identical but of opposite sign. With this method, we found that the water layer next to anatase is spectroscopically similar to ice. This result highlights the potential of electron-yield XAS to obtain chemical and structural information with a high sensitivity for the species at the electrode–electrolyte interface.
000901993 536__ $$0G:(DE-HGF)POF4-632$$a632 - Materials – Quantum, Complex and Functional Materials (POF4-632)$$cPOF4-632$$fPOF IV$$x0
000901993 588__ $$aDataset connected to CrossRef, Journals: juser.fz-juelich.de
000901993 7001_ $$0P:(DE-Juel1)165698$$aZhao, Xiao$$b1
000901993 7001_ $$0P:(DE-HGF)0$$aJaugstetter, Maximilian$$b2
000901993 7001_ $$00000-0001-8716-9391$$aEscudero, Carlos$$b3
000901993 7001_ $$0P:(DE-Juel1)165376$$aDuchoň, Tomáš$$b4
000901993 7001_ $$0P:(DE-HGF)0$$aHunt, Adrian$$b5
000901993 7001_ $$00000-0002-4046-9722$$aWaluyo, Iradwikanari$$b6
000901993 7001_ $$00000-0003-4799-1684$$aYang, Peidong$$b7
000901993 7001_ $$00000-0001-7637-4082$$aTschulik, Kristina$$b8
000901993 7001_ $$00000-0002-2887-8128$$aSalmeron, Miquel B.$$b9$$eCorresponding author
000901993 773__ $$0PERI:(DE-600)2522838-9$$a10.1021/acs.jpclett.1c02115$$gVol. 12, no. 41, p. 10212 - 10217$$n41$$p10212 - 10217$$tThe journal of physical chemistry letters$$v12$$x1948-7185$$y2021
000901993 8564_ $$uhttps://juser.fz-juelich.de/record/901993/files/210613_VanSpronsen-XAS_TIC_TEY.pdf$$yOpenAccess$$zStatID:(DE-HGF)0510
000901993 8564_ $$uhttps://juser.fz-juelich.de/record/901993/files/acs.jpclett.1c02115.pdf$$yRestricted$$zStatID:(DE-HGF)0599
000901993 909CO $$ooai:juser.fz-juelich.de:901993$$pdnbdelivery$$pdriver$$pVDB$$popen_access$$popenaire
000901993 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)165376$$aForschungszentrum Jülich$$b4$$kFZJ
000901993 9131_ $$0G:(DE-HGF)POF4-632$$1G:(DE-HGF)POF4-630$$2G:(DE-HGF)POF4-600$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$aDE-HGF$$bForschungsbereich Materie$$lFrom Matter to Materials and Life$$vMaterials – Quantum, Complex and Functional Materials$$x0
000901993 9141_ $$y2021
000901993 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2021-01-27
000901993 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2021-01-27
000901993 915__ $$0LIC:(DE-HGF)CCBY4$$2HGFVOC$$aCreative Commons Attribution CC BY 4.0
000901993 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bJ PHYS CHEM LETT : 2019$$d2021-01-27
000901993 915__ $$0StatID:(DE-HGF)9905$$2StatID$$aIF >= 5$$bJ PHYS CHEM LETT : 2019$$d2021-01-27
000901993 915__ $$0StatID:(DE-HGF)0113$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2021-01-27
000901993 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2021-01-27
000901993 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000901993 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2021-01-27
000901993 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2021-01-27
000901993 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2021-01-27
000901993 9201_ $$0I:(DE-Juel1)PGI-6-20110106$$kPGI-6$$lElektronische Eigenschaften$$x0
000901993 980__ $$ajournal
000901993 980__ $$aVDB
000901993 980__ $$aUNRESTRICTED
000901993 980__ $$aI:(DE-Juel1)PGI-6-20110106
000901993 9801_ $$aFullTexts