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000902167 1001_ $$00000-0001-9331-5172$$aPabst, Florian$$b0$$eCorresponding author
000902167 245__ $$aEvidence of supercoolable nanoscale water clusters in an amorphous ionic liquid matrix
000902167 260__ $$aMelville, NY$$bAmerican Institute of Physics$$c2021
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000902167 520__ $$aNanoscale water clusters in an ionic liquid matrix, also called “water pockets,” were previously found in some mixtures of water with ionic liquids containing hydrophilic anions. However, in these systems, at least partial crystallization occurs upon supercooling. In this work, we show for mixtures of 1-butyl-3-methylimidazolium dicyanamide with water that none of the components crystallizes up to a water content of 72 mol. %. The dynamics of the ionic liquid matrix is monitored from above room temperature down to the glass transition by combining depolarized dynamic light scattering with broadband dielectric and nuclear magnetic resonance spectroscopy, revealing that the matrix behaves like a common glass former and stays amorphous in the whole temperature range. Moreover, we demonstrate by a combination of Raman spectroscopy, small angle neutron scattering, and molecular dynamics simulation that, indeed, nanoscale water clusters exist in this mixture
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000902167 7001_ $$00000-0001-9267-4907$$aKraus, Jennifer$$b1
000902167 7001_ $$0P:(DE-HGF)0$$aKloth, Sebastian$$b2
000902167 7001_ $$00000-0002-5189-4564$$aSteinrücken, Elisa$$b3
000902167 7001_ $$0P:(DE-Juel1)130777$$aKruteva, Margarita$$b4
000902167 7001_ $$0P:(DE-Juel1)130905$$aRadulescu, Aurel$$b5
000902167 7001_ $$0P:(DE-Juel1)130188$$aVogel, Michael$$b6$$ufzj
000902167 7001_ $$00000-0001-9398-7577$$aBlochowicz, Thomas$$b7$$eCorresponding author
000902167 773__ $$0PERI:(DE-600)1473050-9$$a10.1063/5.0066180$$gVol. 155, no. 17, p. 174501 -$$n17$$p174501$$tThe journal of chemical physics$$v155$$x1089-7690$$y2021
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