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| 001 | 902167 | ||
| 005 | 20240711113552.0 | ||
| 024 | 7 | _ | |a 10.1063/5.0066180 |2 doi |
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| 100 | 1 | _ | |a Pabst, Florian |0 0000-0001-9331-5172 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Evidence of supercoolable nanoscale water clusters in an amorphous ionic liquid matrix |
| 260 | _ | _ | |a Melville, NY |c 2021 |b American Institute of Physics |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 520 | _ | _ | |a Nanoscale water clusters in an ionic liquid matrix, also called “water pockets,” were previously found in some mixtures of water with ionic liquids containing hydrophilic anions. However, in these systems, at least partial crystallization occurs upon supercooling. In this work, we show for mixtures of 1-butyl-3-methylimidazolium dicyanamide with water that none of the components crystallizes up to a water content of 72 mol. %. The dynamics of the ionic liquid matrix is monitored from above room temperature down to the glass transition by combining depolarized dynamic light scattering with broadband dielectric and nuclear magnetic resonance spectroscopy, revealing that the matrix behaves like a common glass former and stays amorphous in the whole temperature range. Moreover, we demonstrate by a combination of Raman spectroscopy, small angle neutron scattering, and molecular dynamics simulation that, indeed, nanoscale water clusters exist in this mixture |
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| 700 | 1 | _ | |a Blochowicz, Thomas |0 0000-0001-9398-7577 |b 7 |e Corresponding author |
| 773 | _ | _ | |a 10.1063/5.0066180 |g Vol. 155, no. 17, p. 174501 - |0 PERI:(DE-600)1473050-9 |n 17 |p 174501 |t The journal of chemical physics |v 155 |y 2021 |x 1089-7690 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/902167/files/5.0066180.pdf |y OpenAccess |
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