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@ARTICLE{Neeman:902287,
      author       = {Neeman, E. M. and González, D. and Blázquez, S. and
                      Ballesteros, B. and Canosa, A. and Antiñolo, M. and
                      Vereecken, L. and Albaladejo, J. and Jiménez, E.},
      title        = {{T}he impact of water vapor on the {OH} reactivity toward
                      {CH} 3 {CHO} at ultra-low temperatures (21.7–135.0 {K}):
                      {E}xperiments and theory},
      journal      = {The journal of chemical physics},
      volume       = {155},
      number       = {3},
      issn         = {1089-7690},
      address      = {Melville, NY},
      publisher    = {American Institute of Physics},
      reportid     = {FZJ-2021-04150},
      pages        = {034306 -},
      year         = {2021},
      abstract     = {The role of water vapor (H2O) and its hydrogen-bonded
                      complexes in the gas-phase reactivity of organic compounds
                      with hydroxyl (OH) radicals has been the subject of many
                      recent studies. Contradictory effects have been reported at
                      temperatures between 200 and 400 K. For the OH +
                      acetaldehyde reaction, a slight catalytic effect of H2O was
                      previously reported at temperatures between 60 and 118 K. In
                      this work, we used Laval nozzle expansions to reinvestigate
                      the impact of H2O on the OH-reactivity with acetaldehyde
                      between 21.7 and 135.0 K. The results of this comprehensive
                      study demonstrate that water, instead, slows down the
                      reaction by factors of ∼3 (21.7 K) and ∼2 (36.2–89.5
                      K), and almost no effect of added H2O was observed at 135.0
                      K},
      cin          = {IEK-8},
      ddc          = {530},
      cid          = {I:(DE-Juel1)IEK-8-20101013},
      pnm          = {2111 - Air Quality (POF4-211)},
      pid          = {G:(DE-HGF)POF4-2111},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {34293904},
      UT           = {WOS:000692367100001},
      doi          = {10.1063/5.0054859},
      url          = {https://juser.fz-juelich.de/record/902287},
}