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@ARTICLE{Shaji:902326,
      author       = {Shaji, Ishamol and Diddens, Diddo and Ehteshami, Niloofar
                      and Winter, Martin and Nair, Jijeesh Ravi},
      title        = {{M}ultisalt chemistry in ion transport and interface of
                      lithium metal polymer batteries},
      journal      = {Energy storage materials},
      volume       = {44},
      issn         = {2405-8297},
      address      = {Amsterdam},
      publisher    = {Elsevier},
      reportid     = {FZJ-2021-04183},
      pages        = {263 - 277},
      year         = {2022},
      abstract     = {Solvent-free solid-state polymer electrolytes (SPE) that go
                      beyond the barriers like intrinsic low ionic conductivity,
                      slow ion dynamics, and unstable electrode-electrolyte
                      interphase will be fundamental for realizing the next
                      generation of safe and high-performance lithium metal
                      batteries. Hereby, cross-linked solid polymer electrolyte
                      (XSPE) networks based on multisalt chemistry are synthesized
                      using photopolymerization reaction, which outshine the
                      conventional single salt-based XSPEs. By introducing the
                      multisalt chemistry, an enhanced Li+ ion transport (ionic
                      conductivity and short residence time) via anion mediated
                      transfer (AMT) and improved interfacial characteristics
                      (e.g., stable Li|electrolyte interphase, smooth
                      Li-deposition) are demonstrated. Furthermore, a three-times
                      increase in Li+ ion transference number and nearly one order
                      of magnitude increment in diffusion coefficient are
                      achieved. Using theoretical calculations, we propose an
                      AMT-based ion conduction pathway in multisalt-based XSPEs.
                      Besides, the superior electrochemical performance of
                      multisalt-based XSPEs compared to single salt-based polymer
                      electrolytes in Li-metal polymer batteries (LMPB) using
                      C-LiFePO4 and LiNi0.8Co0.15Al0.05O2 cathodes are
                      successfully demonstrated.},
      cin          = {IEK-12},
      ddc          = {624},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {1221 - Fundamentals and Materials (POF4-122)},
      pid          = {G:(DE-HGF)POF4-1221},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000718172000007},
      doi          = {10.1016/j.ensm.2021.10.017},
      url          = {https://juser.fz-juelich.de/record/902326},
}