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@ARTICLE{Nussbaumer:902387,
author = {Nussbaumer, Clara M. and Parchatka, Uwe and Tadic, Ivan and
Bohn, Birger and Marno, Daniel and Martinez, Monica and
Rohloff, Roland and Harder, Hartwig and Kluge, Flora and
Pfeilsticker, Klaus and Obersteiner, Florian and Zöger,
Martin and Doerich, Raphael and Crowley, John N. and
Lelieveld, Jos and Fischer, Horst},
title = {{N}ew photolytic converter for improving aircraft
measurements of ${NO}\<sub\>2\</sub\>$ via
chemiluminescence},
journal = {Atmospheric measurement techniques discussions},
issn = {1867-8610},
address = {Katlenburg-Lindau},
publisher = {Copernicus},
reportid = {FZJ-2021-04221},
year = {2021},
abstract = {Abstract. Nitrogen oxides (NOx ≡ NO + NO2) are centrally
involved in the photochemical processes taking place in the
earth’s atmosphere. Measurements of NO2, particularly in
remote areas where concentrations are of the order of pptv,
are still a challenge and subject to extensive research. In
this study, we present NO2 measurements via
photolysis-chemiluminescence during the research aircraft
campaign CAFE Africa (Chemistry of the Atmosphere – Field
Experiment in Africa) 2018 around Cabo Verde as well as the
results of laboratory experiments to characterize the
photolytic converter used. We identify a memory effect
within the conventional photolytic converter associated with
high NO concentrations and rapidly changing water vapor
concentrations, accompanying changes in altitude during
aircraft measurements, which is due to the porous structure
of the converter material. We test and characterize an
alternative photolytic converter made from quartz glass
which improves the reliability of NO2 measurements in
laboratory and field studies.},
cin = {IEK-8},
ddc = {550},
cid = {I:(DE-Juel1)IEK-8-20101013},
pnm = {2111 - Air Quality (POF4-211)},
pid = {G:(DE-HGF)POF4-2111},
typ = {PUB:(DE-HGF)25},
doi = {10.5194/amt-2021-180},
url = {https://juser.fz-juelich.de/record/902387},
}