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000902612 1001_ $$00000-0003-3568-7044$$aJiao, Yushu$$b0
000902612 245__ $$aExploiting complementary ligands for the construction of square antiprismatic monometallic lanthanide SMMs
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000902612 520__ $$aThe methylation of p-tert-butylcalix[4]arene in the distal 1,3-phenolic sites provides the ligand H2L = {p-tert-butylcalix[4](OMe)2(OH)2arene} that enables construction of heteroleptic mononuclear lanthanide complexes. The reaction of (N(nBu)4)(acac) (Hacac = acetylacetone), MIIICl3 and H2L under Schlenk conditions results in the formation of a family of (N(nBu)4)[MIIIL(acac)2] complexes where M = Y (1), Gd (2), Tb (3) and Dy (4). The metal ions are eight-coordinate in distorted square-antiprismatic coordination geometries, resulting in slow relaxation of the magnetisation for the Tb derivative.
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000902612 7001_ $$0P:(DE-Juel1)171755$$aSarwar, Sidra$$b1
000902612 7001_ $$0P:(DE-Juel1)174352$$aSanz, Sergio$$b2
000902612 7001_ $$00000-0003-3688-631X$$avan Leusen, Jan$$b3
000902612 7001_ $$0P:(DE-Juel1)157892$$aIzarova, Natalya V.$$b4
000902612 7001_ $$00000-0003-2617-8491$$aCampbell, Cameron L.$$b5
000902612 7001_ $$00000-0002-9365-370X$$aBrechin, Euan K.$$b6
000902612 7001_ $$00000-0001-7831-012X$$aDalgarno, Scott J.$$b7
000902612 7001_ $$0P:(DE-Juel1)130782$$aKögerler, Paul$$b8$$eCorresponding author
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