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@ARTICLE{Jiao:902612,
      author       = {Jiao, Yushu and Sarwar, Sidra and Sanz, Sergio and van
                      Leusen, Jan and Izarova, Natalya V. and Campbell, Cameron L.
                      and Brechin, Euan K. and Dalgarno, Scott J. and Kögerler,
                      Paul},
      title        = {{E}xploiting complementary ligands for the construction of
                      square antiprismatic monometallic lanthanide {SMM}s},
      journal      = {Dalton transactions},
      volume       = {50},
      number       = {27},
      issn         = {0300-9246},
      address      = {London},
      publisher    = {Soc.},
      reportid     = {FZJ-2021-04407},
      pages        = {9648 - 9654},
      year         = {2021},
      abstract     = {The methylation of p-tert-butylcalix[4]arene in the distal
                      1,3-phenolic sites provides the ligand H2L =
                      {p-tert-butylcalix[4](OMe)2(OH)2arene} that enables
                      construction of heteroleptic mononuclear lanthanide
                      complexes. The reaction of (N(nBu)4)(acac) (Hacac =
                      acetylacetone), MIIICl3 and H2L under Schlenk conditions
                      results in the formation of a family of
                      (N(nBu)4)[MIIIL(acac)2] complexes where M = Y (1), Gd (2),
                      Tb (3) and Dy (4). The metal ions are eight-coordinate in
                      distorted square-antiprismatic coordination geometries,
                      resulting in slow relaxation of the magnetisation for the Tb
                      derivative.},
      cin          = {PGI-6},
      ddc          = {540},
      cid          = {I:(DE-Juel1)PGI-6-20110106},
      pnm          = {5223 - Quantum-Computer Control Systems and Cryoelectronics
                      (POF4-522)},
      pid          = {G:(DE-HGF)POF4-5223},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {34160497},
      UT           = {WOS:000664677600001},
      doi          = {10.1039/D1DT00359C},
      url          = {https://juser.fz-juelich.de/record/902612},
}