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100 1 _ |0 0000-0003-3568-7044
|a Jiao, Yushu
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245 _ _ |a Exploiting complementary ligands for the construction of square antiprismatic monometallic lanthanide SMMs
260 _ _ |a London
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520 _ _ |a The methylation of p-tert-butylcalix[4]arene in the distal 1,3-phenolic sites provides the ligand H2L = {p-tert-butylcalix[4](OMe)2(OH)2arene} that enables construction of heteroleptic mononuclear lanthanide complexes. The reaction of (N(nBu)4)(acac) (Hacac = acetylacetone), MIIICl3 and H2L under Schlenk conditions results in the formation of a family of (N(nBu)4)[MIIIL(acac)2] complexes where M = Y (1), Gd (2), Tb (3) and Dy (4). The metal ions are eight-coordinate in distorted square-antiprismatic coordination geometries, resulting in slow relaxation of the magnetisation for the Tb derivative.
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|a van Leusen, Jan
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856 4 _ |u https://juser.fz-juelich.de/record/902612/files/Sergio_ExploitingComplementaryLigands.pdf
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