| Home > Publications database > Exploiting complementary ligands for the construction of square antiprismatic monometallic lanthanide SMMs > print |
| 001 | 902612 | ||
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| 024 | 7 | _ | |2 doi |a 10.1039/D1DT00359C |
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| 024 | 7 | _ | |2 ISSN |a 1364-5447 |
| 024 | 7 | _ | |2 ISSN |a (2001) |
| 024 | 7 | _ | |2 ISSN |a 1470-479X |
| 024 | 7 | _ | |2 ISSN |a 1477-9226 |
| 024 | 7 | _ | |2 ISSN |a 1477-9234 |
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| 024 | 7 | _ | |2 Handle |a 2128/29338 |
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| 037 | _ | _ | |a FZJ-2021-04407 |
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| 100 | 1 | _ | |0 0000-0003-3568-7044 |a Jiao, Yushu |b 0 |
| 245 | _ | _ | |a Exploiting complementary ligands for the construction of square antiprismatic monometallic lanthanide SMMs |
| 260 | _ | _ | |a London |b Soc. |c 2021 |
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| 520 | _ | _ | |a The methylation of p-tert-butylcalix[4]arene in the distal 1,3-phenolic sites provides the ligand H2L = {p-tert-butylcalix[4](OMe)2(OH)2arene} that enables construction of heteroleptic mononuclear lanthanide complexes. The reaction of (N(nBu)4)(acac) (Hacac = acetylacetone), MIIICl3 and H2L under Schlenk conditions results in the formation of a family of (N(nBu)4)[MIIIL(acac)2] complexes where M = Y (1), Gd (2), Tb (3) and Dy (4). The metal ions are eight-coordinate in distorted square-antiprismatic coordination geometries, resulting in slow relaxation of the magnetisation for the Tb derivative. |
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| 700 | 1 | _ | |0 P:(DE-Juel1)171755 |a Sarwar, Sidra |b 1 |
| 700 | 1 | _ | |0 P:(DE-Juel1)174352 |a Sanz, Sergio |b 2 |
| 700 | 1 | _ | |0 0000-0003-3688-631X |a van Leusen, Jan |b 3 |
| 700 | 1 | _ | |0 P:(DE-Juel1)157892 |a Izarova, Natalya V. |b 4 |
| 700 | 1 | _ | |0 0000-0003-2617-8491 |a Campbell, Cameron L. |b 5 |
| 700 | 1 | _ | |0 0000-0002-9365-370X |a Brechin, Euan K. |b 6 |
| 700 | 1 | _ | |0 0000-0001-7831-012X |a Dalgarno, Scott J. |b 7 |
| 700 | 1 | _ | |0 P:(DE-Juel1)130782 |a Kögerler, Paul |b 8 |e Corresponding author |
| 773 | _ | _ | |0 PERI:(DE-600)1472887-4 |a 10.1039/D1DT00359C |g Vol. 50, no. 27, p. 9648 - 9654 |n 27 |p 9648 - 9654 |t Dalton transactions |v 50 |x 0300-9246 |y 2021 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/902612/files/Sergio_ExploitingComplementaryLigands.pdf |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/902612/files/d1dt00359c-1.pdf |y OpenAccess |
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