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@ARTICLE{Ryzhykau:902966,
author = {Ryzhykau, Yury L. and Vlasov, Alexey V. and Orekhov,
Philipp S. and Rulev, Maksim I. and Rogachev, Andrey V. and
Vlasova, Anastasia D. and Kazantsev, Alexander S. and
Verteletskiy, Dmitry P. and Skoi, Vadim V. and Brennich,
Martha E. and Pernot, Petra and Murugova, Tatiana N. and
Gordeliy, Valentin I. and Kuklin, Alexander I.},
title = {{A}mbiguities in and completeness of {SAS} data analysis of
membrane proteins: the case of the sensory rhodopsin
{II}–transducer complex},
journal = {Acta crystallographica / Section D},
volume = {77},
number = {11},
issn = {0907-4449},
address = {Bognor Regis},
publisher = {Wiley},
reportid = {FZJ-2021-04712},
pages = {1386 - 1400},
year = {2021},
abstract = {Membrane proteins (MPs) play vital roles in the function of
cells and are also major drug targets. Structural
information on proteins is vital for understanding their
mechanism of function and is critical for the development of
drugs. However, obtaining high-resolution structures of
membrane proteins, in particular, under native conditions is
still a great challenge. In such cases, the low-resolution
methods small-angle X-ray and neutron scattering (SAXS and
SANS) might provide valuable structural information.
However, in some cases small-angle scattering (SAS) provides
ambiguous ab initio structural information if complementary
measurements are not performed and/or a priori information
on the protein is not taken into account. Understanding the
nature of the limitations may help to overcome these
problems. One of the main problems of SAS data analysis of
solubilized membrane proteins is the contribution of the
detergent belt surrounding the MP. Here, a comprehensive
analysis of how the detergent belt contributes to the SAS
data of a membrane-protein complex of sensory rhodopsin II
with its cognate transducer from Natronomonas pharaonis
(NpSRII-NpHtrII) was performed. The influence of the
polydispersity of NpSRII-NpHtrII oligomerization is the
second problem that is addressed here. It is shown that
inhomogeneity in the scattering length density of the
detergent belt surrounding a membrane part of the complex
and oligomerization polydispersity significantly impacts on
SAXS and SANS profiles, and therefore on 3D ab initio
structures. It is described how both problems can be taken
into account to improve the quality of SAS data treatment.
Since SAS data for MPs are usually obtained from solubilized
proteins, and their detergent belt and, to a certain extent,
oligomerization polydispersity are sufficiently common
phenomena, the approaches proposed in this work might be
used in SAS studies of different MPs.},
cin = {IBI-7},
ddc = {530},
cid = {I:(DE-Juel1)IBI-7-20200312},
pnm = {5241 - Molecular Information Processing in Cellular Systems
(POF4-524)},
pid = {G:(DE-HGF)POF4-5241},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:34726167},
UT = {WOS:000714429000006},
doi = {10.1107/S2059798321009542},
url = {https://juser.fz-juelich.de/record/902966},
}