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@ARTICLE{Mu:902984,
author = {Mu, Rui and Zheng, Yujie and Lambertz, Andreas and Wilks,
Regan G. and Bär, Marcus and Zhang, Yufeng},
title = {{A} spectrum deconvolution method based on grey relational
analysis},
journal = {Results in Physics},
volume = {23},
issn = {2211-3797},
address = {Amsterdam [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2021-04730},
pages = {104031},
year = {2021},
abstract = {The extensive usage of X-ray spectroscopies in studying
complex material systems is not only intended toreveal
underlying mechanisms that govern physical phenomena, but
also used in applied studies focused onan insight-driven
performance improvement of a wide range of devices. However,
the traditional analysismethods for X-ray spectroscopic data
are rather time-consuming and sensitive to errors in data
preprocessing(e.g., normalization or background
subtraction). In this study, a method based on grey
relationalanalysis, a multi-variable statistical method, is
proposed to analyze and extract information from
X-rayspectroscopic data. As a showcase, the valence bands of
microcrystalline silicon suboxides probed by hardX-ray
photoelectron spectroscopy (HAXPES) were investigated. The
results obtained by the proposedmethod agree well with
conventionally derived composition information (e.g., curve
fit of Si 2p core levelof the silicon suboxides).
Furthermore, the uncertainty of chemical compositions
derived by the proposedmethod is smaller than that of
traditional analysis methods (e.g., the least square fit),
when artificial linearfunctions are introduced to simulate
the errors in data pre-processing. This suggests that the
proposedmethod is capable of providing more reliable and
accurate results, especially for data containing
significantnoise contributions or that is subject to
inconsistent data pre-processing. Since the proposed method
is lessexperience-driven and error-prone, it offers a novel
approach for automate data analysis, which is of
greatinterest for various applications, such as studying
combinatorial material “libraries”.},
cin = {IEK-5},
ddc = {530},
cid = {I:(DE-Juel1)IEK-5-20101013},
pnm = {1213 - Cell Design and Development (POF4-121)},
pid = {G:(DE-HGF)POF4-1213},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000639878400004},
doi = {10.1016/j.rinp.2021.104031},
url = {https://juser.fz-juelich.de/record/902984},
}