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000903120 1001_ $$0P:(DE-HGF)0$$aShen, Hongru$$b0
000903120 245__ $$aHighly Oxygenated Organic Nitrates Formed from NO 3 Radical-Initiated Oxidation of β-Pinene
000903120 260__ $$aColumbus, Ohio$$bAmerican Chemical Society$$c2021
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000903120 520__ $$aThe reactions of biogenic volatile organic compounds (BVOC) with the nitrate radicals (NO3) are major night-time sources of organic nitrates and secondary organic aerosols (SOA) in regions influenced by BVOC and anthropogenic emissions. In this study, the formation of gas-phase highly oxygenated organic molecules-organic nitrates (HOM-ON) from NO3-initiated oxidation of a representative monoterpene, β-pinene, was investigated in the SAPHIR chamber (Simulation of Atmosphere PHotochemistry In a large Reaction chamber). Six monomer (C = 7–10, N = 1–2, O = 6–16) and five accretion product (C = 17–20, N = 2–4, O = 9–22) families were identified and further classified into first- or second-generation products based on their temporal behavior. The time lag observed in the peak concentrations between peroxy radicals containing odd and even number of oxygen atoms, as well as between radicals and their corresponding termination products, provided constraints on the HOM-ON formation mechanism. The HOM-ON formation can be explained by unimolecular or bimolecular reactions of peroxy radicals. A dominant portion of carbonylnitrates in HOM-ON was detected, highlighting the significance of unimolecular termination reactions by intramolecular H-shift for the formation of HOM-ON. A mean molar yield of HOM-ON was estimated to be 4.8% (−2.6%/+5.6%), suggesting significant HOM-ON contributions to the SOA formation.
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000903120 7001_ $$0P:(DE-Juel1)136801$$aZhao, Defeng$$b1$$eCorresponding author
000903120 7001_ $$0P:(DE-Juel1)156385$$aPullinen, Iida$$b2
000903120 7001_ $$0P:(DE-Juel1)169671$$aKang, Sungah$$b3$$ufzj
000903120 7001_ $$0P:(DE-Juel1)167140$$aVereecken, Luc$$b4
000903120 7001_ $$0P:(DE-Juel1)7363$$aFuchs, Hendrik$$b5
000903120 7001_ $$0P:(DE-Juel1)136889$$aAcir, Ismail-Hakki$$b6
000903120 7001_ $$0P:(DE-Juel1)5344$$aTillmann, Ralf$$b7$$ufzj
000903120 7001_ $$0P:(DE-Juel1)16347$$aRohrer, Franz$$b8$$ufzj
000903120 7001_ $$0P:(DE-Juel1)129421$$aWildt, Jürgen$$b9
000903120 7001_ $$0P:(DE-Juel1)4528$$aKiendler-Scharr, Astrid$$b10$$ufzj
000903120 7001_ $$0P:(DE-Juel1)16324$$aWahner, Andreas$$b11$$ufzj
000903120 7001_ $$0P:(DE-Juel1)16346$$aMentel, Thomas F.$$b12$$eCorresponding author$$ufzj
000903120 773__ $$0PERI:(DE-600)1465132-4$$a10.1021/acs.est.1c03978$$gp. acs.est.1c03978$$n32$$p15658–15671$$tEnvironmental science & technology$$v55$$x0013-936X$$y2021
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000903120 8564_ $$uhttps://juser.fz-juelich.de/record/903120/files/Shen_EST_2021ms_postprint.pdf$$yPublished on 2021-11-22. Available in OpenAccess from 2022-11-22.
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