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@ARTICLE{Shen:903120,
      author       = {Shen, Hongru and Zhao, Defeng and Pullinen, Iida and Kang,
                      Sungah and Vereecken, Luc and Fuchs, Hendrik and Acir,
                      Ismail-Hakki and Tillmann, Ralf and Rohrer, Franz and Wildt,
                      Jürgen and Kiendler-Scharr, Astrid and Wahner, Andreas and
                      Mentel, Thomas F.},
      title        = {{H}ighly {O}xygenated {O}rganic {N}itrates {F}ormed from
                      {NO} 3 {R}adical-{I}nitiated {O}xidation of β-{P}inene},
      journal      = {Environmental science $\&$ technology},
      volume       = {55},
      number       = {32},
      issn         = {0013-936X},
      address      = {Columbus, Ohio},
      publisher    = {American Chemical Society},
      reportid     = {FZJ-2021-04844},
      pages        = {15658–15671},
      year         = {2021},
      abstract     = {The reactions of biogenic volatile organic compounds (BVOC)
                      with the nitrate radicals (NO3) are major night-time sources
                      of organic nitrates and secondary organic aerosols (SOA) in
                      regions influenced by BVOC and anthropogenic emissions. In
                      this study, the formation of gas-phase highly oxygenated
                      organic molecules-organic nitrates (HOM-ON) from
                      NO3-initiated oxidation of a representative monoterpene,
                      β-pinene, was investigated in the SAPHIR chamber
                      (Simulation of Atmosphere PHotochemistry In a large Reaction
                      chamber). Six monomer (C = 7–10, N = 1–2, O = 6–16)
                      and five accretion product (C = 17–20, N = 2–4, O =
                      9–22) families were identified and further classified into
                      first- or second-generation products based on their temporal
                      behavior. The time lag observed in the peak concentrations
                      between peroxy radicals containing odd and even number of
                      oxygen atoms, as well as between radicals and their
                      corresponding termination products, provided constraints on
                      the HOM-ON formation mechanism. The HOM-ON formation can be
                      explained by unimolecular or bimolecular reactions of peroxy
                      radicals. A dominant portion of carbonylnitrates in HOM-ON
                      was detected, highlighting the significance of unimolecular
                      termination reactions by intramolecular H-shift for the
                      formation of HOM-ON. A mean molar yield of HOM-ON was
                      estimated to be $4.8\%$ $(−2.6\%/+5.6\%),$ suggesting
                      significant HOM-ON contributions to the SOA formation.},
      cin          = {IEK-8},
      ddc          = {333.7},
      cid          = {I:(DE-Juel1)IEK-8-20101013},
      pnm          = {2111 - Air Quality (POF4-211)},
      pid          = {G:(DE-HGF)POF4-2111},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:34807606},
      UT           = {WOS:000758717600012},
      doi          = {10.1021/acs.est.1c03978},
      url          = {https://juser.fz-juelich.de/record/903120},
}