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@ARTICLE{Pozzer:903145,
author = {Pozzer, Andrea and Reifenberg, Simon and Kumar, Vinod and
Franco, Bruno and Taraborrelli, Domenico and Gromov, Sergy
and Ehrhart, Sebastian and Jöckel, Patrick and Sander, Rolf
and Fall, Veronica and Rosanka, Simon and Karydis, Vlassis
and Akritidis, Dimitris and Emmerichs, Tamara and Crippa,
Monica and Guizzardi, Diego and Kaiser, Johannes W. and
Clarisse, Lieven and Kiendler-Scharr, Astrid and Tost,
Holger and Tsimpidi, Alexandra},
title = {{S}imulation of organics in the atmosphere: evaluation of
{EMAC}v2.54 with the {M}ainz {O}rganic {M}echanism ({MOM})
coupled to the {ORACLE} (v1.0) submodel},
journal = {Geoscientific model development discussions},
issn = {1991-9611},
address = {Katlenburg-Lindau},
publisher = {Copernicus},
reportid = {FZJ-2021-04869},
year = {2021},
abstract = {Abstract. An updated and expanded representation of
organics in the chemistry general circulation model EMAC
(ECHAM5/MESSy for Atmospheric Chemistry) has been evaluated.
First, the comprehensive Mainz Organic Mechanism (MOM) in
the submodel MECCA (Module Efficiently Calculating the
Chemistry of the Atmosphere) was activated with explicit
degradation of organic species up to five carbon atoms and a
simplified mechanism for larger molecules. Second, the
ORACLE submodel (version 1.0) considers now condensation on
aerosols for all organics in the mechanism.
Parameterizations for aerosol yields are used only for the
lumped species that are not included in the explicit
mechanism. The simultaneous usage of MOM and ORACLE allows
an efficient estimation, not only of the chemical
degradation of the simulated volatile organic compounds, but
also of the contribution of organics to the growth and fate
of (organic) aerosol, with a complexity of the mechanism
largely increased compared to EMAC simulations with more
simplified chemistry. The model evaluation presented here
reveals that the OH concentration is well reproduced
globally, while significant biases for observed oxygenated
organics are present. We also investigate the general
properties of the aerosols and their composition, showing
that the more sophisticated and process-oriented secondary
aerosol formation does not degrade the good agreement of
previous model configurations with observations at the
surface, allowing further research in the field of
gas-aerosol interactions.},
cin = {IEK-8},
ddc = {910},
cid = {I:(DE-Juel1)IEK-8-20101013},
pnm = {2111 - Air Quality (POF4-211)},
pid = {G:(DE-HGF)POF4-2111},
typ = {PUB:(DE-HGF)25},
doi = {10.5194/gmd-2021-295},
url = {https://juser.fz-juelich.de/record/903145},
}