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000903155 1001_ $$0P:(DE-Juel1)185890$$aMalgaretti, Paolo$$b0$$eCorresponding author
000903155 245__ $$aTransport of neutral and charged nanorods across varying-section channels
000903155 260__ $$aLondon$$bRoyal Soc. of Chemistry$$c2021
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000903155 520__ $$aWe study the dynamics of neutral and charged rods embedded in varying-section channels. By means of systematic approximations, we derive the dependence of the local diffusion coefficient on both the geometry and charge of the rods. This microscopic insight allows us to provide predictions for the permeability of varying-section channels to rods with diverse lengths, aspect ratios and charge. Our analysis shows that the dynamics of charged rods is sensitive to the geometry of the channel and that their transport can be controlled by tuning both the shape of the confining walls and the charge of the rod. Interestingly, we find that the channel permeability does not depend monotonically on the charge of the rod. This opens the possibility of a novel mechanism to separate charged rods.
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000903155 7001_ $$0P:(DE-Juel1)167472$$aHarting, Jens$$b1
000903155 773__ $$0PERI:(DE-600)2191476-X$$a10.1039/D0SM02045A$$p2062-2070$$tSoft matter$$v17$$x1744-683X$$y2021
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