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@ARTICLE{Wei:903289,
author = {Wei, Xian-Kui and Prokhorenko, Sergei and Wang, Bingqing
and Liu, Zenghui and Xie, Yu-Juan and Nahas, Yousra and Jia,
Chun-Lin and Dunin-Borkowski, Rafal E. and Mayer, Joachim
and Bellaiche, Laurent and Ye, Zuo-Guang},
title = {{F}erroelectric phase-transition frustration near a
tricritical composition point},
journal = {Nature Communications},
volume = {12},
number = {1},
issn = {2041-1723},
address = {[London]},
publisher = {Nature Publishing Group UK},
reportid = {FZJ-2021-04985},
pages = {5322},
year = {2021},
abstract = {Phase transition describes a mutational behavior of matter
states at a critical transition temperature or external
field. Despite the phase-transition orders are well sorted
by classic thermodynamic theory, ambiguous situations
interposed between the first- and second-order transitions
were exposed one after another. Here, we report discovery of
phase-transition frustration near a tricritical composition
point in ferroelectric Pb(Zr1-xTix)O3. Our multi-scale
transmission electron microscopy characterization reveals a
number of geometrically frustrated microstructure features
such as self-assembled hierarchical domain structure,
degeneracy of mesoscale domain tetragonality and decoupled
polarization-strain relationship. Associated with deviation
from the classic mean-field theory, dielectric critical
exponent anomalies and temperature dependent birefringence
data unveil that the frustrated transition order stems from
intricate competition of short-range polar orders and their
decoupling to long-range lattice deformation. With supports
from effective Hamiltonian Monte Carlo simulations, our
findings point out a potentially universal mechanism to
comprehend the abnormal critical phenomena occurring in
phase-transition materials.},
cin = {ER-C-2},
ddc = {500},
cid = {I:(DE-Juel1)ER-C-2-20170209},
pnm = {5353 - Understanding the Structural and Functional Behavior
of Solid State Systems (POF4-535) / DFG project 390534769 -
EXC 2004: Materie und Licht für Quanteninformation (ML4Q)
(390534769)},
pid = {G:(DE-HGF)POF4-5353 / G:(GEPRIS)390534769},
typ = {PUB:(DE-HGF)16},
pubmed = {34493734},
UT = {WOS:000694655700017},
doi = {10.1038/s41467-021-25543-1},
url = {https://juser.fz-juelich.de/record/903289},
}