% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Drr:903293,
      author       = {Dürr, S. and Zilm, S. and Geißelbrecht, M. and Müller,
                      Karsten and Preuster, P. and Bösmann, A. and Wasserscheid,
                      P.},
      title        = {{E}xperimental determination of the
                      hydrogenation/dehydrogenation - {E}quilibrium of the {LOHC}
                      system {H}0/{H}18-dibenzyltoluene},
      journal      = {International journal of hydrogen energy},
      volume       = {46},
      number       = {64},
      issn         = {0360-3199},
      address      = {New York, NY [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2021-04989},
      pages        = {32583 - 32594},
      year         = {2021},
      abstract     = {Liquid organic hydrogen carrier (LOHC) systems store
                      hydrogen through a catalystpromotedexothermal hydrogenation
                      reaction and release hydrogen through an
                      endothermalcatalytic dehydrogenation reaction. At a given
                      pressure and temperature theamount of releasable hydrogen
                      depends on the reaction equilibrium of the
                      hydrogenation/dehydrogenation reaction. Thus, the
                      equilibrium composition of a given LOHC system isone of the
                      key parameters for the reactor and process design of
                      hydrogen storage andrelease units. Currently, LOHC
                      equilibrium data are calculated on the basis of
                      calorimetricdata of selected, pure hydrogen-lean and
                      hydrogen-rich LOHC compounds. Yet, real reactionsystems
                      comprise a variety of isomers, their respective partially
                      hydrogenatedspecies as well as by-products formed during
                      multiple hydrogenation/dehydrogenationcycles. Therefore, our
                      study focuses on an empirical approach to describe the
                      temperatureand pressure dependency of the hydrogenation
                      equilibrium of the LOHC system H0/H18-DBT under real life
                      experimental conditions. Because reliable measurements of
                      the degree of hydrogenation (DoH) play a vital role in this
                      context, we describe in thiscontribution two novel methods
                      of DoH determination for LOHC systems based on 13C NMRand
                      GC-FID measurements.},
      cin          = {IEK-11},
      ddc          = {620},
      cid          = {I:(DE-Juel1)IEK-11-20140314},
      pnm          = {1232 - Power-based Fuels and Chemicals (POF4-123)},
      pid          = {G:(DE-HGF)POF4-1232},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000693237100008},
      doi          = {10.1016/j.ijhydene.2021.07.119},
      url          = {https://juser.fz-juelich.de/record/903293},
}