guest ::
| Home > Publications database > Simultaneous Formation of Interphases on both Positive and Negative Electrodes in High‐Voltage Aqueous Lithium‐Ion Batteries > print |
| Home > Publications database > Simultaneous Formation of Interphases on both Positive and Negative Electrodes in High‐Voltage Aqueous Lithium‐Ion Batteries > print |
| 001 | 903307 | ||
| 005 | 20240712113048.0 | ||
| 024 | 7 | _ | |a 10.1002/smll.202104986 |2 doi |
| 024 | 7 | _ | |a 1613-6810 |2 ISSN |
| 024 | 7 | _ | |a 1613-6829 |2 ISSN |
| 024 | 7 | _ | |a 2128/30716 |2 Handle |
| 024 | 7 | _ | |a altmetric:118013701 |2 altmetric |
| 024 | 7 | _ | |a pmid:34850544 |2 pmid |
| 024 | 7 | _ | |a WOS:000724122200001 |2 WOS |
| 037 | _ | _ | |a FZJ-2021-05003 |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |a Hou, Xu |0 P:(DE-Juel1)173731 |b 0 |u fzj |
| 245 | _ | _ | |a Simultaneous Formation of Interphases on both Positive and Negative Electrodes in High‐Voltage Aqueous Lithium‐Ion Batteries |
| 260 | _ | _ | |a Weinheim |c 2022 |b Wiley-VCH |
| 336 | 7 | _ | |a article |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1645092397_27293 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 520 | _ | _ | |a The formation of solid-electrolyte interphase (SEI) in “water-in-salt” electrolyte (WiSE) expands the electrochemical stability window of aqueous electrolytes beyond 3.0 V. However, the parasitic hydrogen evolution reaction that drives anode corrosion, cracking, and the subsequent reformation of SEI still occurs, compromising long-term cycling performance of the batteries. To improve cycling stability, an unsaturated monomer acrylamide (AM) is introduced as an electrolyte additive, whose presence in WiSE reduces its viscosity and improves ionic conductivity. Upon charging, AM electropolymerizes into polyacrylamide, as confirmed both experimentally and computationally. The in situ polymer constitutes effective protection layers at both anode and cathode surfaces, and enables LiMn2O4||L-TiO2 full cells with high specific capacity (157 mAh g−1 at 1 C), long-term cycling stability (80% capacity retention within 200 cycles at 1 C), and high rate capability (79 mAh g−1 at 30 C). The in situ electropolymerization found in this work provides an alternative and highly effective strategy to design protective interphases at the negative and positive electrodes for high-voltage aqueous batteries of lithium-ion or beyond. |
| 536 | _ | _ | |a 1221 - Fundamentals and Materials (POF4-122) |0 G:(DE-HGF)POF4-1221 |c POF4-122 |f POF IV |x 0 |
| 588 | _ | _ | |a Dataset connected to CrossRef, Journals: juser.fz-juelich.de |
| 700 | 1 | _ | |a Pollard, Travis P. |0 P:(DE-HGF)0 |b 1 |
| 700 | 1 | _ | |a Zhao, Wenguang |0 P:(DE-HGF)0 |b 2 |
| 700 | 1 | _ | |a He, Xin |0 P:(DE-Juel1)169319 |b 3 |e Corresponding author |
| 700 | 1 | _ | |a Ju, Xiaokang |0 P:(DE-Juel1)176763 |b 4 |
| 700 | 1 | _ | |a Wang, Jun |0 P:(DE-Juel1)168392 |b 5 |
| 700 | 1 | _ | |a Du, Leilei |0 P:(DE-HGF)0 |b 6 |
| 700 | 1 | _ | |a Paillard, Elie |0 P:(DE-Juel1)166311 |b 7 |
| 700 | 1 | _ | |a Lin, Hai |0 P:(DE-HGF)0 |b 8 |
| 700 | 1 | _ | |a Xu, Kang |0 P:(DE-HGF)0 |b 9 |
| 700 | 1 | _ | |a Borodin, Oleg |0 P:(DE-HGF)0 |b 10 |e Corresponding author |
| 700 | 1 | _ | |a Winter, Martin |0 P:(DE-Juel1)166130 |b 11 |u fzj |
| 700 | 1 | _ | |a Li, Jie |0 P:(DE-Juel1)174577 |b 12 |e Corresponding author |u fzj |
| 773 | _ | _ | |a 10.1002/smll.202104986 |g p. 2104986 - |0 PERI:(DE-600)2168935-0 |n 5 |p 2104986 - |t Small |v 18 |y 2022 |x 1613-6810 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/903307/files/Small%20-%202021%20-%20Hou%20-%20Simultaneous%20Formation%20of%20Interphases%20on%20both%20Positive%20and%20Negative%20Electrodes%20in%20High%E2%80%90Voltage%20Aqueous.pdf |y OpenAccess |
| 909 | C | O | |o oai:juser.fz-juelich.de:903307 |p openaire |p open_access |p VDB |p driver |p dnbdelivery |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 0 |6 P:(DE-Juel1)173731 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 11 |6 P:(DE-Juel1)166130 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 12 |6 P:(DE-Juel1)174577 |
| 913 | 1 | _ | |a DE-HGF |b Forschungsbereich Energie |l Materialien und Technologien für die Energiewende (MTET) |1 G:(DE-HGF)POF4-120 |0 G:(DE-HGF)POF4-122 |3 G:(DE-HGF)POF4 |2 G:(DE-HGF)POF4-100 |4 G:(DE-HGF)POF |v Elektrochemische Energiespeicherung |9 G:(DE-HGF)POF4-1221 |x 0 |
| 914 | 1 | _ | |y 2022 |
| 915 | _ | _ | |a Creative Commons Attribution-NonCommercial-NoDerivs CC BY-NC-ND 4.0 |0 LIC:(DE-HGF)CCBYNCND4 |2 HGFVOC |
| 915 | _ | _ | |a DEAL Wiley |0 StatID:(DE-HGF)3001 |2 StatID |d 2021-01-27 |w ger |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0113 |2 StatID |b Science Citation Index Expanded |d 2021-01-27 |
| 915 | _ | _ | |a OpenAccess |0 StatID:(DE-HGF)0510 |2 StatID |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0160 |2 StatID |b Essential Science Indicators |d 2021-01-27 |
| 915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |b SMALL : 2021 |d 2022-11-15 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |d 2022-11-15 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |d 2022-11-15 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Clarivate Analytics Master Journal List |d 2022-11-15 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |d 2022-11-15 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1150 |2 StatID |b Current Contents - Physical, Chemical and Earth Sciences |d 2022-11-15 |
| 915 | _ | _ | |a IF >= 15 |0 StatID:(DE-HGF)9915 |2 StatID |b SMALL : 2021 |d 2022-11-15 |
| 920 | _ | _ | |l yes |
| 920 | 1 | _ | |0 I:(DE-Juel1)IEK-12-20141217 |k IEK-12 |l Helmholtz-Institut Münster Ionenleiter für Energiespeicher |x 0 |
| 980 | 1 | _ | |a FullTexts |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a I:(DE-Juel1)IEK-12-20141217 |
| 980 | _ | _ | |a UNRESTRICTED |
| 981 | _ | _ | |a I:(DE-Juel1)IMD-4-20141217 |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|